Chiral Brønsted acid-controlled intermolecular asymmetric [2 + 2] photocycloadditions
Lewis acids have recently been shown to enable stereocontrol in photochemical cycloadditions, a difficult task due to the reactivity of excited-state compounds. Here the authors show that chiral Brønsted acids are competent chromophore activators in [2+2] cycloadditions, forming diastereomers disfav...
Guardado en:
Autores principales: | Evan M. Sherbrook, Matthew J. Genzink, Bohyun Park, Ilia A. Guzei, Mu-Hyun Baik, Tehshik P. Yoon |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2021
|
Materias: | |
Acceso en línea: | https://doaj.org/article/1908ce6f531f444cbbef8ded72f8a70f |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Chirality imprinting and direct asymmetric reaction screening using a stereodynamic Brønsted/Lewis acid receptor
por: Keith W. Bentley, et al.
Publicado: (2016) -
Asymmetric C(sp3)–H functionalization of unactivated alkylarenes such as toluene enabled by chiral Brønsted base catalysts
por: Tsubasa Hirata, et al.
Publicado: (2021) -
Brønsted acid-catalysed enantioselective construction of axially chiral arylquinazolinones
por: Yong-Bin Wang, et al.
Publicado: (2017) -
Unusual piezochromic fluorescence of a distyrylpyrazine derivative crystals: phase transition through [2 + 2] photocycloaddition under UV irradiation
por: Young-Jae Jin, et al.
Publicado: (2021) -
Permanent porous hydrogen-bonded frameworks with two types of Brønsted acid sites for heterogeneous asymmetric catalysis
por: Wei Gong, et al.
Publicado: (2019)