Chiral Brønsted acid-controlled intermolecular asymmetric [2 + 2] photocycloadditions
Lewis acids have recently been shown to enable stereocontrol in photochemical cycloadditions, a difficult task due to the reactivity of excited-state compounds. Here the authors show that chiral Brønsted acids are competent chromophore activators in [2+2] cycloadditions, forming diastereomers disfav...
Saved in:
Main Authors: | Evan M. Sherbrook, Matthew J. Genzink, Bohyun Park, Ilia A. Guzei, Mu-Hyun Baik, Tehshik P. Yoon |
---|---|
Format: | article |
Language: | EN |
Published: |
Nature Portfolio
2021
|
Subjects: | |
Online Access: | https://doaj.org/article/1908ce6f531f444cbbef8ded72f8a70f |
Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
Similar Items
-
Chirality imprinting and direct asymmetric reaction screening using a stereodynamic Brønsted/Lewis acid receptor
by: Keith W. Bentley, et al.
Published: (2016) -
Asymmetric C(sp3)–H functionalization of unactivated alkylarenes such as toluene enabled by chiral Brønsted base catalysts
by: Tsubasa Hirata, et al.
Published: (2021) -
Brønsted acid-catalysed enantioselective construction of axially chiral arylquinazolinones
by: Yong-Bin Wang, et al.
Published: (2017) -
Unusual piezochromic fluorescence of a distyrylpyrazine derivative crystals: phase transition through [2 + 2] photocycloaddition under UV irradiation
by: Young-Jae Jin, et al.
Published: (2021) -
Permanent porous hydrogen-bonded frameworks with two types of Brønsted acid sites for heterogeneous asymmetric catalysis
by: Wei Gong, et al.
Published: (2019)