Convective meniscus splitting of polysaccharide microparticles on various surfaces
Abstract In contrast to convective self-assembly methods for colloidal crystals etc., “convective meniscus splitting method” was developed to fabricate three-dimensionally ordered polymeric structures. By controlling the geometry of evaporative interface of polymer solution, a deposited membrane wit...
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Nature Portfolio
2021
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oai:doaj.org-article:196c006f7aca4adcbc744d92547f6bae2021-12-02T14:01:21ZConvective meniscus splitting of polysaccharide microparticles on various surfaces10.1038/s41598-020-80779-z2045-2322https://doaj.org/article/196c006f7aca4adcbc744d92547f6bae2021-01-01T00:00:00Zhttps://doi.org/10.1038/s41598-020-80779-zhttps://doaj.org/toc/2045-2322Abstract In contrast to convective self-assembly methods for colloidal crystals etc., “convective meniscus splitting method” was developed to fabricate three-dimensionally ordered polymeric structures. By controlling the geometry of evaporative interface of polymer solution, a deposited membrane with uniaxial orientation and layered structures can be prepared. Here it is demonstrated that xanthan gum polysaccharide microparticles with diameter ~ 1 µm can bridge a millimeter-scale gap to form such a membrane because the capillary force among the particles is more dominant than the gravitational force on the evaporative interface. This method is applicable for various substrates with a wide range of wettability (water contact angle, 11°–111°), such as glass, metals, and plastics. The specific deposition can be also confirmed between frosted glasses, functional-molecules-modified glasses, and gold-sputtered substrates. By using such a universal method, the membrane formed on a polydimethylsiloxane surface using this method will provide a new strategy to design a functional polysaccharide wall in microfluidic devices, such as mass-separators.Kosuke OkeyoshiMiki YamashitaKulisara BudpudGargi JoshiTatsuo KanekoNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 11, Iss 1, Pp 1-7 (2021) |
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Medicine R Science Q Kosuke Okeyoshi Miki Yamashita Kulisara Budpud Gargi Joshi Tatsuo Kaneko Convective meniscus splitting of polysaccharide microparticles on various surfaces |
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Abstract In contrast to convective self-assembly methods for colloidal crystals etc., “convective meniscus splitting method” was developed to fabricate three-dimensionally ordered polymeric structures. By controlling the geometry of evaporative interface of polymer solution, a deposited membrane with uniaxial orientation and layered structures can be prepared. Here it is demonstrated that xanthan gum polysaccharide microparticles with diameter ~ 1 µm can bridge a millimeter-scale gap to form such a membrane because the capillary force among the particles is more dominant than the gravitational force on the evaporative interface. This method is applicable for various substrates with a wide range of wettability (water contact angle, 11°–111°), such as glass, metals, and plastics. The specific deposition can be also confirmed between frosted glasses, functional-molecules-modified glasses, and gold-sputtered substrates. By using such a universal method, the membrane formed on a polydimethylsiloxane surface using this method will provide a new strategy to design a functional polysaccharide wall in microfluidic devices, such as mass-separators. |
format |
article |
author |
Kosuke Okeyoshi Miki Yamashita Kulisara Budpud Gargi Joshi Tatsuo Kaneko |
author_facet |
Kosuke Okeyoshi Miki Yamashita Kulisara Budpud Gargi Joshi Tatsuo Kaneko |
author_sort |
Kosuke Okeyoshi |
title |
Convective meniscus splitting of polysaccharide microparticles on various surfaces |
title_short |
Convective meniscus splitting of polysaccharide microparticles on various surfaces |
title_full |
Convective meniscus splitting of polysaccharide microparticles on various surfaces |
title_fullStr |
Convective meniscus splitting of polysaccharide microparticles on various surfaces |
title_full_unstemmed |
Convective meniscus splitting of polysaccharide microparticles on various surfaces |
title_sort |
convective meniscus splitting of polysaccharide microparticles on various surfaces |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/196c006f7aca4adcbc744d92547f6bae |
work_keys_str_mv |
AT kosukeokeyoshi convectivemeniscussplittingofpolysaccharidemicroparticlesonvarioussurfaces AT mikiyamashita convectivemeniscussplittingofpolysaccharidemicroparticlesonvarioussurfaces AT kulisarabudpud convectivemeniscussplittingofpolysaccharidemicroparticlesonvarioussurfaces AT gargijoshi convectivemeniscussplittingofpolysaccharidemicroparticlesonvarioussurfaces AT tatsuokaneko convectivemeniscussplittingofpolysaccharidemicroparticlesonvarioussurfaces |
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