Kinetic resolution of indolines by asymmetric hydroxylamine formation
Catalytic kinetic resolution of amines is a longstanding challenge in chemical synthesis. Here, the authors report on titanium‐catalysed asymmetric oxygenation with hydrogen peroxide for kinetic resolution of secondary amines through oxygenation to produce enantiopure hydroxylamines involving N–O bo...
Guardado en:
Autores principales: | , , , |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2021
|
Materias: | |
Acceso en línea: | https://doaj.org/article/199565172e374220bfd17d35397fec04 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
id |
oai:doaj.org-article:199565172e374220bfd17d35397fec04 |
---|---|
record_format |
dspace |
spelling |
oai:doaj.org-article:199565172e374220bfd17d35397fec042021-12-02T14:29:13ZKinetic resolution of indolines by asymmetric hydroxylamine formation10.1038/s41467-021-22658-32041-1723https://doaj.org/article/199565172e374220bfd17d35397fec042021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22658-3https://doaj.org/toc/2041-1723Catalytic kinetic resolution of amines is a longstanding challenge in chemical synthesis. Here, the authors report on titanium‐catalysed asymmetric oxygenation with hydrogen peroxide for kinetic resolution of secondary amines through oxygenation to produce enantiopure hydroxylamines involving N–O bond formation.Gang WangRan LuChuangchuang HeLei LiuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021) |
institution |
DOAJ |
collection |
DOAJ |
language |
EN |
topic |
Science Q |
spellingShingle |
Science Q Gang Wang Ran Lu Chuangchuang He Lei Liu Kinetic resolution of indolines by asymmetric hydroxylamine formation |
description |
Catalytic kinetic resolution of amines is a longstanding challenge in chemical synthesis. Here, the authors report on titanium‐catalysed asymmetric oxygenation with hydrogen peroxide for kinetic resolution of secondary amines through oxygenation to produce enantiopure hydroxylamines involving N–O bond formation. |
format |
article |
author |
Gang Wang Ran Lu Chuangchuang He Lei Liu |
author_facet |
Gang Wang Ran Lu Chuangchuang He Lei Liu |
author_sort |
Gang Wang |
title |
Kinetic resolution of indolines by asymmetric hydroxylamine formation |
title_short |
Kinetic resolution of indolines by asymmetric hydroxylamine formation |
title_full |
Kinetic resolution of indolines by asymmetric hydroxylamine formation |
title_fullStr |
Kinetic resolution of indolines by asymmetric hydroxylamine formation |
title_full_unstemmed |
Kinetic resolution of indolines by asymmetric hydroxylamine formation |
title_sort |
kinetic resolution of indolines by asymmetric hydroxylamine formation |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/199565172e374220bfd17d35397fec04 |
work_keys_str_mv |
AT gangwang kineticresolutionofindolinesbyasymmetrichydroxylamineformation AT ranlu kineticresolutionofindolinesbyasymmetrichydroxylamineformation AT chuangchuanghe kineticresolutionofindolinesbyasymmetrichydroxylamineformation AT leiliu kineticresolutionofindolinesbyasymmetrichydroxylamineformation |
_version_ |
1718391176663400448 |