Kinetic resolution of indolines by asymmetric hydroxylamine formation

Catalytic kinetic resolution of amines is a longstanding challenge in chemical synthesis. Here, the authors report on titanium‐catalysed asymmetric oxygenation with hydrogen peroxide for kinetic resolution of secondary amines through oxygenation to produce enantiopure hydroxylamines involving N–O bo...

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Autores principales: Gang Wang, Ran Lu, Chuangchuang He, Lei Liu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/199565172e374220bfd17d35397fec04
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spelling oai:doaj.org-article:199565172e374220bfd17d35397fec042021-12-02T14:29:13ZKinetic resolution of indolines by asymmetric hydroxylamine formation10.1038/s41467-021-22658-32041-1723https://doaj.org/article/199565172e374220bfd17d35397fec042021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22658-3https://doaj.org/toc/2041-1723Catalytic kinetic resolution of amines is a longstanding challenge in chemical synthesis. Here, the authors report on titanium‐catalysed asymmetric oxygenation with hydrogen peroxide for kinetic resolution of secondary amines through oxygenation to produce enantiopure hydroxylamines involving N–O bond formation.Gang WangRan LuChuangchuang HeLei LiuNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-11 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Gang Wang
Ran Lu
Chuangchuang He
Lei Liu
Kinetic resolution of indolines by asymmetric hydroxylamine formation
description Catalytic kinetic resolution of amines is a longstanding challenge in chemical synthesis. Here, the authors report on titanium‐catalysed asymmetric oxygenation with hydrogen peroxide for kinetic resolution of secondary amines through oxygenation to produce enantiopure hydroxylamines involving N–O bond formation.
format article
author Gang Wang
Ran Lu
Chuangchuang He
Lei Liu
author_facet Gang Wang
Ran Lu
Chuangchuang He
Lei Liu
author_sort Gang Wang
title Kinetic resolution of indolines by asymmetric hydroxylamine formation
title_short Kinetic resolution of indolines by asymmetric hydroxylamine formation
title_full Kinetic resolution of indolines by asymmetric hydroxylamine formation
title_fullStr Kinetic resolution of indolines by asymmetric hydroxylamine formation
title_full_unstemmed Kinetic resolution of indolines by asymmetric hydroxylamine formation
title_sort kinetic resolution of indolines by asymmetric hydroxylamine formation
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/199565172e374220bfd17d35397fec04
work_keys_str_mv AT gangwang kineticresolutionofindolinesbyasymmetrichydroxylamineformation
AT ranlu kineticresolutionofindolinesbyasymmetrichydroxylamineformation
AT chuangchuanghe kineticresolutionofindolinesbyasymmetrichydroxylamineformation
AT leiliu kineticresolutionofindolinesbyasymmetrichydroxylamineformation
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