New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes
We have obtained a series of low-dimensional hybrid perovskitoids (often referred to as perovskites) based on lead bromide. As organic cations, the derivatives of polyaromatic and conjugated molecules, such as anthracene, pyrene and (E)-stilbene, were chosen to form charge-transfer complexes with va...
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oai:doaj.org-article:19b5321975264443a94fb0cac09e7a562021-11-25T17:19:39ZNew Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes10.3390/cryst111114242073-4352https://doaj.org/article/19b5321975264443a94fb0cac09e7a562021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4352/11/11/1424https://doaj.org/toc/2073-4352We have obtained a series of low-dimensional hybrid perovskitoids (often referred to as perovskites) based on lead bromide. As organic cations, the derivatives of polyaromatic and conjugated molecules, such as anthracene, pyrene and (E)-stilbene, were chosen to form charge-transfer complexes with various organic acceptors for use as highly tunable components of hybrid perovskite solar cells. X-ray diffraction analysis showed these crystalline materials to be new 1D- and pseudo-layered 0D-perovskitoids with lead bromide octahedra featuring different sharing modes, such as in unusual mini-rods of four face- and edge-shared octahedra. Thanks to the low dimensionality, they can be of use in another type of optoelectronic device, photodetectors.Igor A. NikovskiyKseniya L. IsakovskayaYulia V. NelyubinaMDPI AGarticlelead bromidelow-dimensional perovskiteshybrid perovskitescharge-transfer complexesperovskitoidssolar cellsCrystallographyQD901-999ENCrystals, Vol 11, Iss 1424, p 1424 (2021) |
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lead bromide low-dimensional perovskites hybrid perovskites charge-transfer complexes perovskitoids solar cells Crystallography QD901-999 |
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lead bromide low-dimensional perovskites hybrid perovskites charge-transfer complexes perovskitoids solar cells Crystallography QD901-999 Igor A. Nikovskiy Kseniya L. Isakovskaya Yulia V. Nelyubina New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
description |
We have obtained a series of low-dimensional hybrid perovskitoids (often referred to as perovskites) based on lead bromide. As organic cations, the derivatives of polyaromatic and conjugated molecules, such as anthracene, pyrene and (E)-stilbene, were chosen to form charge-transfer complexes with various organic acceptors for use as highly tunable components of hybrid perovskite solar cells. X-ray diffraction analysis showed these crystalline materials to be new 1D- and pseudo-layered 0D-perovskitoids with lead bromide octahedra featuring different sharing modes, such as in unusual mini-rods of four face- and edge-shared octahedra. Thanks to the low dimensionality, they can be of use in another type of optoelectronic device, photodetectors. |
format |
article |
author |
Igor A. Nikovskiy Kseniya L. Isakovskaya Yulia V. Nelyubina |
author_facet |
Igor A. Nikovskiy Kseniya L. Isakovskaya Yulia V. Nelyubina |
author_sort |
Igor A. Nikovskiy |
title |
New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
title_short |
New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
title_full |
New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
title_fullStr |
New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
title_full_unstemmed |
New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes |
title_sort |
new low-dimensional hybrid perovskitoids based on lead bromide with organic cations from charge-transfer complexes |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/19b5321975264443a94fb0cac09e7a56 |
work_keys_str_mv |
AT igoranikovskiy newlowdimensionalhybridperovskitoidsbasedonleadbromidewithorganiccationsfromchargetransfercomplexes AT kseniyalisakovskaya newlowdimensionalhybridperovskitoidsbasedonleadbromidewithorganiccationsfromchargetransfercomplexes AT yuliavnelyubina newlowdimensionalhybridperovskitoidsbasedonleadbromidewithorganiccationsfromchargetransfercomplexes |
_version_ |
1718412453802409984 |