New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes

We have obtained a series of low-dimensional hybrid perovskitoids (often referred to as perovskites) based on lead bromide. As organic cations, the derivatives of polyaromatic and conjugated molecules, such as anthracene, pyrene and (E)-stilbene, were chosen to form charge-transfer complexes with va...

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Autores principales: Igor A. Nikovskiy, Kseniya L. Isakovskaya, Yulia V. Nelyubina
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Publicado: MDPI AG 2021
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spelling oai:doaj.org-article:19b5321975264443a94fb0cac09e7a562021-11-25T17:19:39ZNew Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes10.3390/cryst111114242073-4352https://doaj.org/article/19b5321975264443a94fb0cac09e7a562021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4352/11/11/1424https://doaj.org/toc/2073-4352We have obtained a series of low-dimensional hybrid perovskitoids (often referred to as perovskites) based on lead bromide. As organic cations, the derivatives of polyaromatic and conjugated molecules, such as anthracene, pyrene and (E)-stilbene, were chosen to form charge-transfer complexes with various organic acceptors for use as highly tunable components of hybrid perovskite solar cells. X-ray diffraction analysis showed these crystalline materials to be new 1D- and pseudo-layered 0D-perovskitoids with lead bromide octahedra featuring different sharing modes, such as in unusual mini-rods of four face- and edge-shared octahedra. Thanks to the low dimensionality, they can be of use in another type of optoelectronic device, photodetectors.Igor A. NikovskiyKseniya L. IsakovskayaYulia V. NelyubinaMDPI AGarticlelead bromidelow-dimensional perovskiteshybrid perovskitescharge-transfer complexesperovskitoidssolar cellsCrystallographyQD901-999ENCrystals, Vol 11, Iss 1424, p 1424 (2021)
institution DOAJ
collection DOAJ
language EN
topic lead bromide
low-dimensional perovskites
hybrid perovskites
charge-transfer complexes
perovskitoids
solar cells
Crystallography
QD901-999
spellingShingle lead bromide
low-dimensional perovskites
hybrid perovskites
charge-transfer complexes
perovskitoids
solar cells
Crystallography
QD901-999
Igor A. Nikovskiy
Kseniya L. Isakovskaya
Yulia V. Nelyubina
New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes
description We have obtained a series of low-dimensional hybrid perovskitoids (often referred to as perovskites) based on lead bromide. As organic cations, the derivatives of polyaromatic and conjugated molecules, such as anthracene, pyrene and (E)-stilbene, were chosen to form charge-transfer complexes with various organic acceptors for use as highly tunable components of hybrid perovskite solar cells. X-ray diffraction analysis showed these crystalline materials to be new 1D- and pseudo-layered 0D-perovskitoids with lead bromide octahedra featuring different sharing modes, such as in unusual mini-rods of four face- and edge-shared octahedra. Thanks to the low dimensionality, they can be of use in another type of optoelectronic device, photodetectors.
format article
author Igor A. Nikovskiy
Kseniya L. Isakovskaya
Yulia V. Nelyubina
author_facet Igor A. Nikovskiy
Kseniya L. Isakovskaya
Yulia V. Nelyubina
author_sort Igor A. Nikovskiy
title New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes
title_short New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes
title_full New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes
title_fullStr New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes
title_full_unstemmed New Low-Dimensional Hybrid Perovskitoids Based on Lead Bromide with Organic Cations from Charge-Transfer Complexes
title_sort new low-dimensional hybrid perovskitoids based on lead bromide with organic cations from charge-transfer complexes
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/19b5321975264443a94fb0cac09e7a56
work_keys_str_mv AT igoranikovskiy newlowdimensionalhybridperovskitoidsbasedonleadbromidewithorganiccationsfromchargetransfercomplexes
AT kseniyalisakovskaya newlowdimensionalhybridperovskitoidsbasedonleadbromidewithorganiccationsfromchargetransfercomplexes
AT yuliavnelyubina newlowdimensionalhybridperovskitoidsbasedonleadbromidewithorganiccationsfromchargetransfercomplexes
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