One-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives

Fullerenes are intrinsically electron deficient species which can facilitate challenging transformations in organic chemistry. Here fullerene-fused alkoxy ethers are shown to undergo copper-promoted oxidation by single electron transfer to the corresponding ketones via a fullerene radical cation int...

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Autores principales:	Hao-Sheng Lin, Yue Ma, Rong Xiang, Sergei Manzhos, Il Jeon, Shigeo Maruyama, Yutaka Matsuo
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/1a3cfcb969b44daf9513b22ed695c682
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spelling	oai:doaj.org-article:1a3cfcb969b44daf9513b22ed695c6822021-12-02T15:52:51ZOne-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives10.1038/s42004-021-00511-42399-3669https://doaj.org/article/1a3cfcb969b44daf9513b22ed695c6822021-05-01T00:00:00Zhttps://doi.org/10.1038/s42004-021-00511-4https://doaj.org/toc/2399-3669Fullerenes are intrinsically electron deficient species which can facilitate challenging transformations in organic chemistry. Here fullerene-fused alkoxy ethers are shown to undergo copper-promoted oxidation by single electron transfer to the corresponding ketones via a fullerene radical cation intermediate.Hao-Sheng LinYue MaRong XiangSergei ManzhosIl JeonShigeo MaruyamaYutaka MatsuoNature PortfolioarticleChemistryQD1-999ENCommunications Chemistry, Vol 4, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Chemistry QD1-999
spellingShingle	Chemistry QD1-999 Hao-Sheng Lin Yue Ma Rong Xiang Sergei Manzhos Il Jeon Shigeo Maruyama Yutaka Matsuo One-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives
description	Fullerenes are intrinsically electron deficient species which can facilitate challenging transformations in organic chemistry. Here fullerene-fused alkoxy ethers are shown to undergo copper-promoted oxidation by single electron transfer to the corresponding ketones via a fullerene radical cation intermediate.
format	article
author	Hao-Sheng Lin Yue Ma Rong Xiang Sergei Manzhos Il Jeon Shigeo Maruyama Yutaka Matsuo
author_facet	Hao-Sheng Lin Yue Ma Rong Xiang Sergei Manzhos Il Jeon Shigeo Maruyama Yutaka Matsuo
author_sort	Hao-Sheng Lin
title	One-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives
title_short	One-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives
title_full	One-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives
title_fullStr	One-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives
title_full_unstemmed	One-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives
title_sort	one-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/1a3cfcb969b44daf9513b22ed695c682
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One-step direct oxidation of fullerene-fused alkoxy ethers to ketones for evaporable fullerene derivatives

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