γ-Selective C(sp3)–H amination via controlled migratory hydroamination

Sequential alkene isomerization and cross-coupling enables remote functionalization, but coupling has been limited to positions at a carbon chain terminus or proximal to a functional group. Here the authors show a method to interrupt isomerization with a nickellacycle, which enables coupling at an a...

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Autores principales:	Changseok Lee, Huiyeong Seo, Jinwon Jeon, Sungwoo Hong
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/1a60ac28c7e04920bacdea2f1b1d2f18
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spelling	oai:doaj.org-article:1a60ac28c7e04920bacdea2f1b1d2f182021-12-02T17:18:32Zγ-Selective C(sp3)–H amination via controlled migratory hydroamination10.1038/s41467-021-25696-z2041-1723https://doaj.org/article/1a60ac28c7e04920bacdea2f1b1d2f182021-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25696-zhttps://doaj.org/toc/2041-1723Sequential alkene isomerization and cross-coupling enables remote functionalization, but coupling has been limited to positions at a carbon chain terminus or proximal to a functional group. Here the authors show a method to interrupt isomerization with a nickellacycle, which enables coupling at an atypical, unreactive position.Changseok LeeHuiyeong SeoJinwon JeonSungwoo HongNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-9 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Changseok Lee Huiyeong Seo Jinwon Jeon Sungwoo Hong γ-Selective C(sp3)–H amination via controlled migratory hydroamination
description	Sequential alkene isomerization and cross-coupling enables remote functionalization, but coupling has been limited to positions at a carbon chain terminus or proximal to a functional group. Here the authors show a method to interrupt isomerization with a nickellacycle, which enables coupling at an atypical, unreactive position.
format	article
author	Changseok Lee Huiyeong Seo Jinwon Jeon Sungwoo Hong
author_facet	Changseok Lee Huiyeong Seo Jinwon Jeon Sungwoo Hong
author_sort	Changseok Lee
title	γ-Selective C(sp3)–H amination via controlled migratory hydroamination
title_short	γ-Selective C(sp3)–H amination via controlled migratory hydroamination
title_full	γ-Selective C(sp3)–H amination via controlled migratory hydroamination
title_fullStr	γ-Selective C(sp3)–H amination via controlled migratory hydroamination
title_full_unstemmed	γ-Selective C(sp3)–H amination via controlled migratory hydroamination
title_sort	γ-selective c(sp3)–h amination via controlled migratory hydroamination
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/1a60ac28c7e04920bacdea2f1b1d2f18
work_keys_str_mv	AT changseoklee gselectivecsp3haminationviacontrolledmigratoryhydroamination AT huiyeongseo gselectivecsp3haminationviacontrolledmigratoryhydroamination AT jinwonjeon gselectivecsp3haminationviacontrolledmigratoryhydroamination AT sungwoohong gselectivecsp3haminationviacontrolledmigratoryhydroamination
_version_	1718381069878689792

γ-Selective C(sp3)–H amination via controlled migratory hydroamination

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