γ-Selective C(sp3)–H amination via controlled migratory hydroamination
Sequential alkene isomerization and cross-coupling enables remote functionalization, but coupling has been limited to positions at a carbon chain terminus or proximal to a functional group. Here the authors show a method to interrupt isomerization with a nickellacycle, which enables coupling at an a...
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Autores principales: | Changseok Lee, Huiyeong Seo, Jinwon Jeon, Sungwoo Hong |
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Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2021
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Materias: | |
Acceso en línea: | https://doaj.org/article/1a60ac28c7e04920bacdea2f1b1d2f18 |
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