Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers
In biological systems it is common for molecular chirality to be expressed at the macroscopic level, but such translation is difficult to achieve in synthetic systems. Here, the authors synthesise homochiral terbium-based coordination polymers with both helical and crystalline morphologies.
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Nature Portfolio
2017
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oai:doaj.org-article:1a793248e3684d7d941bf1137a0594572021-12-02T14:40:37ZChiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers10.1038/s41467-017-02260-22041-1723https://doaj.org/article/1a793248e3684d7d941bf1137a0594572017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02260-2https://doaj.org/toc/2041-1723In biological systems it is common for molecular chirality to be expressed at the macroscopic level, but such translation is difficult to achieve in synthetic systems. Here, the authors synthesise homochiral terbium-based coordination polymers with both helical and crystalline morphologies.Jian HuangHong-ming DingYan XuDai ZengHui ZhuDong-Mian ZangSong-Song BaoYu-qiang MaLi-Min ZhengNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-12 (2017) |
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Science Q Jian Huang Hong-ming Ding Yan Xu Dai Zeng Hui Zhu Dong-Mian Zang Song-Song Bao Yu-qiang Ma Li-Min Zheng Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers |
description |
In biological systems it is common for molecular chirality to be expressed at the macroscopic level, but such translation is difficult to achieve in synthetic systems. Here, the authors synthesise homochiral terbium-based coordination polymers with both helical and crystalline morphologies. |
format |
article |
author |
Jian Huang Hong-ming Ding Yan Xu Dai Zeng Hui Zhu Dong-Mian Zang Song-Song Bao Yu-qiang Ma Li-Min Zheng |
author_facet |
Jian Huang Hong-ming Ding Yan Xu Dai Zeng Hui Zhu Dong-Mian Zang Song-Song Bao Yu-qiang Ma Li-Min Zheng |
author_sort |
Jian Huang |
title |
Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers |
title_short |
Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers |
title_full |
Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers |
title_fullStr |
Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers |
title_full_unstemmed |
Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers |
title_sort |
chiral expression from molecular to macroscopic level via ph modulation in terbium coordination polymers |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/1a793248e3684d7d941bf1137a059457 |
work_keys_str_mv |
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1718390219745525760 |