Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers

In biological systems it is common for molecular chirality to be expressed at the macroscopic level, but such translation is difficult to achieve in synthetic systems. Here, the authors synthesise homochiral terbium-based coordination polymers with both helical and crystalline morphologies.

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Autores principales: Jian Huang, Hong-ming Ding, Yan Xu, Dai Zeng, Hui Zhu, Dong-Mian Zang, Song-Song Bao, Yu-qiang Ma, Li-Min Zheng
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Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/1a793248e3684d7d941bf1137a059457
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spelling oai:doaj.org-article:1a793248e3684d7d941bf1137a0594572021-12-02T14:40:37ZChiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers10.1038/s41467-017-02260-22041-1723https://doaj.org/article/1a793248e3684d7d941bf1137a0594572017-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-02260-2https://doaj.org/toc/2041-1723In biological systems it is common for molecular chirality to be expressed at the macroscopic level, but such translation is difficult to achieve in synthetic systems. Here, the authors synthesise homochiral terbium-based coordination polymers with both helical and crystalline morphologies.Jian HuangHong-ming DingYan XuDai ZengHui ZhuDong-Mian ZangSong-Song BaoYu-qiang MaLi-Min ZhengNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-12 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jian Huang
Hong-ming Ding
Yan Xu
Dai Zeng
Hui Zhu
Dong-Mian Zang
Song-Song Bao
Yu-qiang Ma
Li-Min Zheng
Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers
description In biological systems it is common for molecular chirality to be expressed at the macroscopic level, but such translation is difficult to achieve in synthetic systems. Here, the authors synthesise homochiral terbium-based coordination polymers with both helical and crystalline morphologies.
format article
author Jian Huang
Hong-ming Ding
Yan Xu
Dai Zeng
Hui Zhu
Dong-Mian Zang
Song-Song Bao
Yu-qiang Ma
Li-Min Zheng
author_facet Jian Huang
Hong-ming Ding
Yan Xu
Dai Zeng
Hui Zhu
Dong-Mian Zang
Song-Song Bao
Yu-qiang Ma
Li-Min Zheng
author_sort Jian Huang
title Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers
title_short Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers
title_full Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers
title_fullStr Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers
title_full_unstemmed Chiral expression from molecular to macroscopic level via pH modulation in terbium coordination polymers
title_sort chiral expression from molecular to macroscopic level via ph modulation in terbium coordination polymers
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/1a793248e3684d7d941bf1137a059457
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AT yuqiangma chiralexpressionfrommoleculartomacroscopiclevelviaphmodulationinterbiumcoordinationpolymers
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