δ and φ back-donation in AnIV metallacycles

Metal-ligand δ and φ interactions, though considered weak, may be necessary for fully describing the electronic and geometric structures of certain compounds. Here, in actinide metallacycles, the authors discover two new types of M-L δ and φ back-bonds that contribute substantially to their unusual...

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Autores principales:	Morgan P. Kelley, Ivan A. Popov, Julie Jung, Enrique R. Batista, Ping Yang
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/1ac9337d22ce41bab1de99b341e254bf
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id	oai:doaj.org-article:1ac9337d22ce41bab1de99b341e254bf
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spelling	oai:doaj.org-article:1ac9337d22ce41bab1de99b341e254bf2021-12-02T16:49:27Zδ and φ back-donation in AnIV metallacycles10.1038/s41467-020-15197-w2041-1723https://doaj.org/article/1ac9337d22ce41bab1de99b341e254bf2020-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15197-whttps://doaj.org/toc/2041-1723Metal-ligand δ and φ interactions, though considered weak, may be necessary for fully describing the electronic and geometric structures of certain compounds. Here, in actinide metallacycles, the authors discover two new types of M-L δ and φ back-bonds that contribute substantially to their unusual chemical behavior.Morgan P. KelleyIvan A. PopovJulie JungEnrique R. BatistaPing YangNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Morgan P. Kelley Ivan A. Popov Julie Jung Enrique R. Batista Ping Yang δ and φ back-donation in AnIV metallacycles
description	Metal-ligand δ and φ interactions, though considered weak, may be necessary for fully describing the electronic and geometric structures of certain compounds. Here, in actinide metallacycles, the authors discover two new types of M-L δ and φ back-bonds that contribute substantially to their unusual chemical behavior.
format	article
author	Morgan P. Kelley Ivan A. Popov Julie Jung Enrique R. Batista Ping Yang
author_facet	Morgan P. Kelley Ivan A. Popov Julie Jung Enrique R. Batista Ping Yang
author_sort	Morgan P. Kelley
title	δ and φ back-donation in AnIV metallacycles
title_short	δ and φ back-donation in AnIV metallacycles
title_full	δ and φ back-donation in AnIV metallacycles
title_fullStr	δ and φ back-donation in AnIV metallacycles
title_full_unstemmed	δ and φ back-donation in AnIV metallacycles
title_sort	δ and φ back-donation in aniv metallacycles
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/1ac9337d22ce41bab1de99b341e254bf
work_keys_str_mv	AT morganpkelley dandphbackdonationinanivmetallacycles AT ivanapopov dandphbackdonationinanivmetallacycles AT juliejung dandphbackdonationinanivmetallacycles AT enriquerbatista dandphbackdonationinanivmetallacycles AT pingyang dandphbackdonationinanivmetallacycles
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δ and φ back-donation in AnIV metallacycles

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