Improving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis

The direct synthesis of hydrogen peroxide from molecular H2 and O2 offers an attractive alternative to the current means of production of this powerful oxidant, on an industrial scale. Herein we investigate the role of nitric acid addition, during catalyst preparation as a means of improving catalyt...

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Autores principales:	Richard J. Lewis, Edwin N. Ntainjua, David J. Morgan, Thomas E. Davies, Albert F. Carley, Simon J. Freakley, Graham J. Hutchings
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Palladium H2O2 direct synthesis Green chemistry Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/1aee3e00a3354e378f0686e16fc30a30
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spelling	oai:doaj.org-article:1aee3e00a3354e378f0686e16fc30a302021-11-16T04:09:14ZImproving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis1873-390510.1016/j.catcom.2021.106358https://doaj.org/article/1aee3e00a3354e378f0686e16fc30a302021-12-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S1566736721000819https://doaj.org/toc/1873-3905The direct synthesis of hydrogen peroxide from molecular H2 and O2 offers an attractive alternative to the current means of production of this powerful oxidant, on an industrial scale. Herein we investigate the role of nitric acid addition, during catalyst preparation as a means of improving catalytic performance, under reaction conditions that have previously been found to be optimal for H2O2 production. The addition of dilute nitric acid during catalyst preparation is found to lead to a significant improvement in H2O2 synthesis activity, through the modification of particle size and control of Pd oxidation state.Richard J. LewisEdwin N. NtainjuaDavid J. MorganThomas E. DaviesAlbert F. CarleySimon J. FreakleyGraham J. HutchingsElsevierarticlePalladiumH2O2 direct synthesisGreen chemistryChemistryQD1-999ENCatalysis Communications, Vol 161, Iss , Pp 106358- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Palladium H2O2 direct synthesis Green chemistry Chemistry QD1-999
spellingShingle	Palladium H2O2 direct synthesis Green chemistry Chemistry QD1-999 Richard J. Lewis Edwin N. Ntainjua David J. Morgan Thomas E. Davies Albert F. Carley Simon J. Freakley Graham J. Hutchings Improving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis
description	The direct synthesis of hydrogen peroxide from molecular H2 and O2 offers an attractive alternative to the current means of production of this powerful oxidant, on an industrial scale. Herein we investigate the role of nitric acid addition, during catalyst preparation as a means of improving catalytic performance, under reaction conditions that have previously been found to be optimal for H2O2 production. The addition of dilute nitric acid during catalyst preparation is found to lead to a significant improvement in H2O2 synthesis activity, through the modification of particle size and control of Pd oxidation state.
format	article
author	Richard J. Lewis Edwin N. Ntainjua David J. Morgan Thomas E. Davies Albert F. Carley Simon J. Freakley Graham J. Hutchings
author_facet	Richard J. Lewis Edwin N. Ntainjua David J. Morgan Thomas E. Davies Albert F. Carley Simon J. Freakley Graham J. Hutchings
author_sort	Richard J. Lewis
title	Improving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis
title_short	Improving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis
title_full	Improving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis
title_fullStr	Improving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis
title_full_unstemmed	Improving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis
title_sort	improving the performance of pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/1aee3e00a3354e378f0686e16fc30a30
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Improving the performance of Pd based catalysts for the direct synthesis of hydrogen peroxide via acid incorporation during catalyst synthesis

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