Photoelectrochemical Conversion of Methane into Value-Added Products

Methane has been reported to be directly converted into value-added products through various methods. Among them, photoelectrochemical (PEC) methane conversion is considered an eco-friendly method because it utilizes solar light and is able to control the selectivity to different products by means o...

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Autores principales: Adeel Mehmood, Sang Youn Chae, Eun Duck Park
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Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/1b196c7a8b594c7192eafedb6571a925
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spelling oai:doaj.org-article:1b196c7a8b594c7192eafedb6571a9252021-11-25T17:06:39ZPhotoelectrochemical Conversion of Methane into Value-Added Products10.3390/catal111113872073-4344https://doaj.org/article/1b196c7a8b594c7192eafedb6571a9252021-11-01T00:00:00Zhttps://www.mdpi.com/2073-4344/11/11/1387https://doaj.org/toc/2073-4344Methane has been reported to be directly converted into value-added products through various methods. Among them, photoelectrochemical (PEC) methane conversion is considered an eco-friendly method because it utilizes solar light and is able to control the selectivity to different products by means of application of an external bias. Recently, some PEC methane conversion systems have been reported, but their performance efficiencies are relatively lower than those of other existing thermal, photocatalytic, and electrochemical systems. The detailed mechanism of methane activation is not clear at this stage. In this review, various catalytic materials and their roles in the reaction pathways are summarized and discussed. Furthermore, promising semiconductor materials, co-catalysts, and oxidants have also been proposed. Finally, direct and indirect pathways in the design of the PEC methane conversion system have been discussed.Adeel MehmoodSang Youn ChaeEun Duck ParkMDPI AGarticlemethane activationphotoelectrochemical conversionoxidationmethanolformic acidChemical technologyTP1-1185ChemistryQD1-999ENCatalysts, Vol 11, Iss 1387, p 1387 (2021)
institution DOAJ
collection DOAJ
language EN
topic methane activation
photoelectrochemical conversion
oxidation
methanol
formic acid
Chemical technology
TP1-1185
Chemistry
QD1-999
spellingShingle methane activation
photoelectrochemical conversion
oxidation
methanol
formic acid
Chemical technology
TP1-1185
Chemistry
QD1-999
Adeel Mehmood
Sang Youn Chae
Eun Duck Park
Photoelectrochemical Conversion of Methane into Value-Added Products
description Methane has been reported to be directly converted into value-added products through various methods. Among them, photoelectrochemical (PEC) methane conversion is considered an eco-friendly method because it utilizes solar light and is able to control the selectivity to different products by means of application of an external bias. Recently, some PEC methane conversion systems have been reported, but their performance efficiencies are relatively lower than those of other existing thermal, photocatalytic, and electrochemical systems. The detailed mechanism of methane activation is not clear at this stage. In this review, various catalytic materials and their roles in the reaction pathways are summarized and discussed. Furthermore, promising semiconductor materials, co-catalysts, and oxidants have also been proposed. Finally, direct and indirect pathways in the design of the PEC methane conversion system have been discussed.
format article
author Adeel Mehmood
Sang Youn Chae
Eun Duck Park
author_facet Adeel Mehmood
Sang Youn Chae
Eun Duck Park
author_sort Adeel Mehmood
title Photoelectrochemical Conversion of Methane into Value-Added Products
title_short Photoelectrochemical Conversion of Methane into Value-Added Products
title_full Photoelectrochemical Conversion of Methane into Value-Added Products
title_fullStr Photoelectrochemical Conversion of Methane into Value-Added Products
title_full_unstemmed Photoelectrochemical Conversion of Methane into Value-Added Products
title_sort photoelectrochemical conversion of methane into value-added products
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/1b196c7a8b594c7192eafedb6571a925
work_keys_str_mv AT adeelmehmood photoelectrochemicalconversionofmethaneintovalueaddedproducts
AT sangyounchae photoelectrochemicalconversionofmethaneintovalueaddedproducts
AT eunduckpark photoelectrochemicalconversionofmethaneintovalueaddedproducts
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