Site-selective remote C(sp3)–H heteroarylation of amides via organic photoredox catalysis
Nitrogen-centered radicals are valuable intermediates for the controllable and selective functionalization of remote inert C(sp3)–H bonds. Here, the authors report an amidyl radical-triggered, metal-free and site-selective C(sp3)–H heteroarylation of amides under photoredox conditions.
Guardado en:
Autores principales: | Hui Chen, Wenjing Fan, Xiang-Ai Yuan, Shouyun Yu |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2019
|
Materias: | |
Acceso en línea: | https://doaj.org/article/1b9945378c72441bb7b2843a65f6e788 |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Direct C–H difluoromethylation of heterocycles via organic photoredox catalysis
por: Wei Zhang, et al.
Publicado: (2020) -
Asymmetric benzylic C(sp3)−H acylation via dual nickel and photoredox catalysis
por: Leitao Huan, et al.
Publicado: (2021) -
Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp3)–H bonds
por: Xinxin Wu, et al.
Publicado: (2018) -
Benzylic C−H acylation by cooperative NHC and photoredox catalysis
por: Qing-Yuan Meng, et al.
Publicado: (2021) -
syn-Selective alkylarylation of terminal alkynes via the combination of photoredox and nickel catalysis
por: Lei Guo, et al.
Publicado: (2018)