Pyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO4 (X = Cl, Mn, Re) Compounds

We reviewed the synthesis, structure, and properties of pyridine complexes of AgXO4 (X = Cl, Mn, and Re) compounds with various compositions ([AgPy2] XO4, [AgPy2XO4]·0.5Py, [AgPy<sub...

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Autores principales:	Fernanda Paiva Franguelli, Kende Attila Béres, Laszló Kótai
Formato:	article
Lenguaje:	EN
Publicado:	MDPI AG 2021
Materias:	silver complexes permanganates perchlorates perrhenate pyridine structure Inorganic chemistry QD146-197
Acceso en línea:	https://doaj.org/article/1be73cdbb10f4a8981f9ea1083a569c8
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spelling	oai:doaj.org-article:1be73cdbb10f4a8981f9ea1083a569c82021-11-25T17:58:57ZPyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO<sub>4</sub> (X = Cl, Mn, Re) Compounds10.3390/inorganics91100792304-6740https://doaj.org/article/1be73cdbb10f4a8981f9ea1083a569c82021-10-01T00:00:00Zhttps://www.mdpi.com/2304-6740/9/11/79https://doaj.org/toc/2304-6740We reviewed the synthesis, structure, and properties of pyridine complexes of AgXO<sub>4</sub> (X = Cl, Mn, and Re) compounds with various compositions ([AgPy<sub>2</sub>] XO<sub>4</sub>, [AgPy<sub>2</sub>XO<sub>4</sub>]·0.5Py, [AgPy<sub>4</sub>] XO<sub>4</sub>, and 4 [AgPy<sub>2</sub>XO<sub>4</sub>] [AgPy<sub>4</sub>] XO<sub>4</sub>). We also clarified the controversial information about the existence and composition of pyridine complexes of silver permanganate, used widely as mild and selective oxidants in organic chemistry. We discussed in detail the available structural and spectroscopic (IR, Raman, and UV) data and thermal behavior, including the existence and consequence of quasi-intramolecular reactions between the reducing ligand and anions containing oxygen.Fernanda Paiva FranguelliKende Attila BéresLaszló KótaiMDPI AGarticlesilver complexespermanganatesperchloratesperrhenatepyridinestructureInorganic chemistryQD146-197ENInorganics, Vol 9, Iss 79, p 79 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	silver complexes permanganates perchlorates perrhenate pyridine structure Inorganic chemistry QD146-197
spellingShingle	silver complexes permanganates perchlorates perrhenate pyridine structure Inorganic chemistry QD146-197 Fernanda Paiva Franguelli Kende Attila Béres Laszló Kótai Pyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO<sub>4</sub> (X = Cl, Mn, Re) Compounds
description	We reviewed the synthesis, structure, and properties of pyridine complexes of AgXO<sub>4</sub> (X = Cl, Mn, and Re) compounds with various compositions ([AgPy<sub>2</sub>] XO<sub>4</sub>, [AgPy<sub>2</sub>XO<sub>4</sub>]·0.5Py, [AgPy<sub>4</sub>] XO<sub>4</sub>, and 4 [AgPy<sub>2</sub>XO<sub>4</sub>] [AgPy<sub>4</sub>] XO<sub>4</sub>). We also clarified the controversial information about the existence and composition of pyridine complexes of silver permanganate, used widely as mild and selective oxidants in organic chemistry. We discussed in detail the available structural and spectroscopic (IR, Raman, and UV) data and thermal behavior, including the existence and consequence of quasi-intramolecular reactions between the reducing ligand and anions containing oxygen.
format	article
author	Fernanda Paiva Franguelli Kende Attila Béres Laszló Kótai
author_facet	Fernanda Paiva Franguelli Kende Attila Béres Laszló Kótai
author_sort	Fernanda Paiva Franguelli
title	Pyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO<sub>4</sub> (X = Cl, Mn, Re) Compounds
title_short	Pyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO<sub>4</sub> (X = Cl, Mn, Re) Compounds
title_full	Pyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO<sub>4</sub> (X = Cl, Mn, Re) Compounds
title_fullStr	Pyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO<sub>4</sub> (X = Cl, Mn, Re) Compounds
title_full_unstemmed	Pyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO<sub>4</sub> (X = Cl, Mn, Re) Compounds
title_sort	pyridinesilver tetraoxometallate complexes: overview of the synthesis, structure, and properties of pyridine complexed agxo<sub>4</sub> (x = cl, mn, re) compounds
publisher	MDPI AG
publishDate	2021
url	https://doaj.org/article/1be73cdbb10f4a8981f9ea1083a569c8
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Pyridinesilver Tetraoxometallate Complexes: Overview of the Synthesis, Structure, and Properties of Pyridine Complexed AgXO<sub>4</sub> (X = Cl, Mn, Re) Compounds

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