Fabrication of Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> Nanocomposite for Detection of H<sub>2</sub>O<sub>2</sub> and Dopamine
Herein, the Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> nanocomposite has been prepared as a novel electrochemical sensor to accurately detect hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) and glucose. ZIF-67 is a...
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MDPI AG
2021
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oai:doaj.org-article:1c1dc73684f247a3b1884ab592e0976c2021-11-25T16:55:35ZFabrication of Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> Nanocomposite for Detection of H<sub>2</sub>O<sub>2</sub> and Dopamine10.3390/bios111104522079-6374https://doaj.org/article/1c1dc73684f247a3b1884ab592e0976c2021-11-01T00:00:00Zhttps://www.mdpi.com/2079-6374/11/11/452https://doaj.org/toc/2079-6374Herein, the Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> nanocomposite has been prepared as a novel electrochemical sensor to accurately detect hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) and glucose. ZIF-67 is a metal-organic framework (MOF) with Co as the center metal ion. Co<sub>3</sub>O<sub>4</sub> can be obtained by calcination of ZIF-67 at 700 °C, which can retain the structure of ZIF-67. The hollow Co<sub>3</sub>O<sub>4</sub> nanocrystal was synthesized based on a calcination process of ZIF-67. This open structure can promote the whole Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> nanocomposite larger accessible surface area and reactive sites. Co<sub>3</sub>O<sub>4</sub> has good electrocatalytic performance, which has been applied in many fields. Moreover, H<sub>2</sub>O<sub>2</sub> and dopamine sensing tests indicate that the as-prepared non-enzymatic electrochemical biosensor has good detection properties. The testing results indicate the as-prepared biosensor has a wide detection range, low detection limit, high selectivity, and long-term stability. These testing results suggest the potential application in food security, biomedicine, environmental detection, and pharmaceutical analysis.Tianjiao LiuXiaoyuan ZhangKun FuNan ZhouJinping XiongZhiqiang SuMDPI AGarticleZIF-67Co<sub>3</sub>O<sub>4</sub>NiCo<sub>2</sub>O<sub>4</sub>electrochemical biosensorH<sub>2</sub>O<sub>2</sub>dopamineBiotechnologyTP248.13-248.65ENBiosensors, Vol 11, Iss 452, p 452 (2021) |
institution |
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DOAJ |
language |
EN |
topic |
ZIF-67 Co<sub>3</sub>O<sub>4</sub> NiCo<sub>2</sub>O<sub>4</sub> electrochemical biosensor H<sub>2</sub>O<sub>2</sub> dopamine Biotechnology TP248.13-248.65 |
spellingShingle |
ZIF-67 Co<sub>3</sub>O<sub>4</sub> NiCo<sub>2</sub>O<sub>4</sub> electrochemical biosensor H<sub>2</sub>O<sub>2</sub> dopamine Biotechnology TP248.13-248.65 Tianjiao Liu Xiaoyuan Zhang Kun Fu Nan Zhou Jinping Xiong Zhiqiang Su Fabrication of Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> Nanocomposite for Detection of H<sub>2</sub>O<sub>2</sub> and Dopamine |
description |
Herein, the Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> nanocomposite has been prepared as a novel electrochemical sensor to accurately detect hydrogen peroxide (H<sub>2</sub>O<sub>2</sub>) and glucose. ZIF-67 is a metal-organic framework (MOF) with Co as the center metal ion. Co<sub>3</sub>O<sub>4</sub> can be obtained by calcination of ZIF-67 at 700 °C, which can retain the structure of ZIF-67. The hollow Co<sub>3</sub>O<sub>4</sub> nanocrystal was synthesized based on a calcination process of ZIF-67. This open structure can promote the whole Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> nanocomposite larger accessible surface area and reactive sites. Co<sub>3</sub>O<sub>4</sub> has good electrocatalytic performance, which has been applied in many fields. Moreover, H<sub>2</sub>O<sub>2</sub> and dopamine sensing tests indicate that the as-prepared non-enzymatic electrochemical biosensor has good detection properties. The testing results indicate the as-prepared biosensor has a wide detection range, low detection limit, high selectivity, and long-term stability. These testing results suggest the potential application in food security, biomedicine, environmental detection, and pharmaceutical analysis. |
format |
article |
author |
Tianjiao Liu Xiaoyuan Zhang Kun Fu Nan Zhou Jinping Xiong Zhiqiang Su |
author_facet |
Tianjiao Liu Xiaoyuan Zhang Kun Fu Nan Zhou Jinping Xiong Zhiqiang Su |
author_sort |
Tianjiao Liu |
title |
Fabrication of Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> Nanocomposite for Detection of H<sub>2</sub>O<sub>2</sub> and Dopamine |
title_short |
Fabrication of Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> Nanocomposite for Detection of H<sub>2</sub>O<sub>2</sub> and Dopamine |
title_full |
Fabrication of Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> Nanocomposite for Detection of H<sub>2</sub>O<sub>2</sub> and Dopamine |
title_fullStr |
Fabrication of Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> Nanocomposite for Detection of H<sub>2</sub>O<sub>2</sub> and Dopamine |
title_full_unstemmed |
Fabrication of Co<sub>3</sub>O<sub>4</sub>/NiCo<sub>2</sub>O<sub>4</sub> Nanocomposite for Detection of H<sub>2</sub>O<sub>2</sub> and Dopamine |
title_sort |
fabrication of co<sub>3</sub>o<sub>4</sub>/nico<sub>2</sub>o<sub>4</sub> nanocomposite for detection of h<sub>2</sub>o<sub>2</sub> and dopamine |
publisher |
MDPI AG |
publishDate |
2021 |
url |
https://doaj.org/article/1c1dc73684f247a3b1884ab592e0976c |
work_keys_str_mv |
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1718412822572957696 |