Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
So far, only a few chemical oscillators based on organic reactions have been developed. Here, the authors report both autocatalytic and oscillatory reaction networks that form substituted guanidines from thiouronium salts; when coupled to cascade cyclization, this reaction network produces oscillati...
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Nature Portfolio
2021
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oai:doaj.org-article:1c6275c48f0e4de699754dd9efaad4e82021-12-02T15:52:59ZAutocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization10.1038/s41467-021-23206-92041-1723https://doaj.org/article/1c6275c48f0e4de699754dd9efaad4e82021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23206-9https://doaj.org/toc/2041-1723So far, only a few chemical oscillators based on organic reactions have been developed. Here, the authors report both autocatalytic and oscillatory reaction networks that form substituted guanidines from thiouronium salts; when coupled to cascade cyclization, this reaction network produces oscillations in the production of pyrimidine-based heterocycles.Alexander I. NovichkovAnton I. HanopolskyiXiaoming MiaoLinda J. W. ShimonYael Diskin-PosnerSergey N. SemenovNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-13 (2021) |
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Science Q Alexander I. Novichkov Anton I. Hanopolskyi Xiaoming Miao Linda J. W. Shimon Yael Diskin-Posner Sergey N. Semenov Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization |
description |
So far, only a few chemical oscillators based on organic reactions have been developed. Here, the authors report both autocatalytic and oscillatory reaction networks that form substituted guanidines from thiouronium salts; when coupled to cascade cyclization, this reaction network produces oscillations in the production of pyrimidine-based heterocycles. |
format |
article |
author |
Alexander I. Novichkov Anton I. Hanopolskyi Xiaoming Miao Linda J. W. Shimon Yael Diskin-Posner Sergey N. Semenov |
author_facet |
Alexander I. Novichkov Anton I. Hanopolskyi Xiaoming Miao Linda J. W. Shimon Yael Diskin-Posner Sergey N. Semenov |
author_sort |
Alexander I. Novichkov |
title |
Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization |
title_short |
Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization |
title_full |
Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization |
title_fullStr |
Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization |
title_full_unstemmed |
Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization |
title_sort |
autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/1c6275c48f0e4de699754dd9efaad4e8 |
work_keys_str_mv |
AT alexanderinovichkov autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization AT antonihanopolskyi autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization AT xiaomingmiao autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization AT lindajwshimon autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization AT yaeldiskinposner autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization AT sergeynsemenov autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization |
_version_ |
1718385497600950272 |