Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization

So far, only a few chemical oscillators based on organic reactions have been developed. Here, the authors report both autocatalytic and oscillatory reaction networks that form substituted guanidines from thiouronium salts; when coupled to cascade cyclization, this reaction network produces oscillati...

Descripción completa

Guardado en:
Detalles Bibliográficos
Autores principales: Alexander I. Novichkov, Anton I. Hanopolskyi, Xiaoming Miao, Linda J. W. Shimon, Yael Diskin-Posner, Sergey N. Semenov
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
Materias:
Q
Acceso en línea:https://doaj.org/article/1c6275c48f0e4de699754dd9efaad4e8
Etiquetas: Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
id oai:doaj.org-article:1c6275c48f0e4de699754dd9efaad4e8
record_format dspace
spelling oai:doaj.org-article:1c6275c48f0e4de699754dd9efaad4e82021-12-02T15:52:59ZAutocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization10.1038/s41467-021-23206-92041-1723https://doaj.org/article/1c6275c48f0e4de699754dd9efaad4e82021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-23206-9https://doaj.org/toc/2041-1723So far, only a few chemical oscillators based on organic reactions have been developed. Here, the authors report both autocatalytic and oscillatory reaction networks that form substituted guanidines from thiouronium salts; when coupled to cascade cyclization, this reaction network produces oscillations in the production of pyrimidine-based heterocycles.Alexander I. NovichkovAnton I. HanopolskyiXiaoming MiaoLinda J. W. ShimonYael Diskin-PosnerSergey N. SemenovNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-13 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Alexander I. Novichkov
Anton I. Hanopolskyi
Xiaoming Miao
Linda J. W. Shimon
Yael Diskin-Posner
Sergey N. Semenov
Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
description So far, only a few chemical oscillators based on organic reactions have been developed. Here, the authors report both autocatalytic and oscillatory reaction networks that form substituted guanidines from thiouronium salts; when coupled to cascade cyclization, this reaction network produces oscillations in the production of pyrimidine-based heterocycles.
format article
author Alexander I. Novichkov
Anton I. Hanopolskyi
Xiaoming Miao
Linda J. W. Shimon
Yael Diskin-Posner
Sergey N. Semenov
author_facet Alexander I. Novichkov
Anton I. Hanopolskyi
Xiaoming Miao
Linda J. W. Shimon
Yael Diskin-Posner
Sergey N. Semenov
author_sort Alexander I. Novichkov
title Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_short Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_full Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_fullStr Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_full_unstemmed Autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
title_sort autocatalytic and oscillatory reaction networks that form guanidines and products of their cyclization
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/1c6275c48f0e4de699754dd9efaad4e8
work_keys_str_mv AT alexanderinovichkov autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization
AT antonihanopolskyi autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization
AT xiaomingmiao autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization
AT lindajwshimon autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization
AT yaeldiskinposner autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization
AT sergeynsemenov autocatalyticandoscillatoryreactionnetworksthatformguanidinesandproductsoftheircyclization
_version_ 1718385497600950272