NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY

Five new oxalato and hydrogenoxalato complexes with ZnBr2 have been synthesized and studied by infrared. Discrete structures have been suggested in the basis of spectroscopic data. The environments around the zinc centre being trigonal bipyramidal, tetrahedral, octahedral or monocapped octahedral....

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Autores principales: GORGUI AWA SECK, LIBASSE DIOP, ABOUBACRY SENE
Formato: article
Lenguaje:EN
Publicado: Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2017
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Acceso en línea:https://doaj.org/article/1c73aff41aa84bfba57ab95c340286ac
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spelling oai:doaj.org-article:1c73aff41aa84bfba57ab95c340286ac2021-12-02T19:52:43ZNEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY10.29081/jesr.v23i3.782068-75592344-4932https://doaj.org/article/1c73aff41aa84bfba57ab95c340286ac2017-09-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/78https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 Five new oxalato and hydrogenoxalato complexes with ZnBr2 have been synthesized and studied by infrared. Discrete structures have been suggested in the basis of spectroscopic data. The environments around the zinc centre being trigonal bipyramidal, tetrahedral, octahedral or monocapped octahedral. The anions behave as monochelating ligands. When the cations and OH group are involved in extra hydrogen bonds, a supramolecular architecture may be obtained. GORGUI AWA SECKLIBASSE DIOPABOUBACRY SENEAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticlediscrete structureshydrogen bondsIR technicmonochelating oxoanionsmonocapped octahedraloxalato and hydrogenoxalato complexesTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 23, Iss 3 (2017)
institution DOAJ
collection DOAJ
language EN
topic discrete structures
hydrogen bonds
IR technic
monochelating oxoanions
monocapped octahedral
oxalato and hydrogenoxalato complexes
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
spellingShingle discrete structures
hydrogen bonds
IR technic
monochelating oxoanions
monocapped octahedral
oxalato and hydrogenoxalato complexes
Technology
T
Engineering (General). Civil engineering (General)
TA1-2040
GORGUI AWA SECK
LIBASSE DIOP
ABOUBACRY SENE
NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY
description Five new oxalato and hydrogenoxalato complexes with ZnBr2 have been synthesized and studied by infrared. Discrete structures have been suggested in the basis of spectroscopic data. The environments around the zinc centre being trigonal bipyramidal, tetrahedral, octahedral or monocapped octahedral. The anions behave as monochelating ligands. When the cations and OH group are involved in extra hydrogen bonds, a supramolecular architecture may be obtained.
format article
author GORGUI AWA SECK
LIBASSE DIOP
ABOUBACRY SENE
author_facet GORGUI AWA SECK
LIBASSE DIOP
ABOUBACRY SENE
author_sort GORGUI AWA SECK
title NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY
title_short NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY
title_full NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY
title_fullStr NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY
title_full_unstemmed NEW ZINC OXALATO AND HYDROGENOXALATO COMPLEXES: SYNTHESIS AND INFRARED STUDY
title_sort new zinc oxalato and hydrogenoxalato complexes: synthesis and infrared study
publisher Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
publishDate 2017
url https://doaj.org/article/1c73aff41aa84bfba57ab95c340286ac
work_keys_str_mv AT gorguiawaseck newzincoxalatoandhydrogenoxalatocomplexessynthesisandinfraredstudy
AT libassediop newzincoxalatoandhydrogenoxalatocomplexessynthesisandinfraredstudy
AT aboubacrysene newzincoxalatoandhydrogenoxalatocomplexessynthesisandinfraredstudy
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