Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water
The efficiency of chemical reactions in biological systems is often connected to the properties of confined water, but the developments and applications of artificial mimicking systems are impeded by the complexity of the biological systems. Here, the authors show how surface bound water in nanoporo...
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Nature Portfolio
2021
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oai:doaj.org-article:1c87f8e079b5460aad80641c6577d9ce2021-12-02T14:29:01ZUnique reactivity of nanoporous cellulosic materials mediated by surface-confined water10.1038/s41467-021-22682-32041-1723https://doaj.org/article/1c87f8e079b5460aad80641c6577d9ce2021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22682-3https://doaj.org/toc/2041-1723The efficiency of chemical reactions in biological systems is often connected to the properties of confined water, but the developments and applications of artificial mimicking systems are impeded by the complexity of the biological systems. Here, the authors show how surface bound water in nanoporous cellulosic fibers can increase the reaction rate of surface acetylation reactions and enable regioselectivity of the reactionMarco BeaumontPaul JusnerNotburga GierlingerAlistair W. T. KingAntje PotthastOrlando J. RojasThomas RosenauNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021) |
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Science Q |
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Science Q Marco Beaumont Paul Jusner Notburga Gierlinger Alistair W. T. King Antje Potthast Orlando J. Rojas Thomas Rosenau Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water |
description |
The efficiency of chemical reactions in biological systems is often connected to the properties of confined water, but the developments and applications of artificial mimicking systems are impeded by the complexity of the biological systems. Here, the authors show how surface bound water in nanoporous cellulosic fibers can increase the reaction rate of surface acetylation reactions and enable regioselectivity of the reaction |
format |
article |
author |
Marco Beaumont Paul Jusner Notburga Gierlinger Alistair W. T. King Antje Potthast Orlando J. Rojas Thomas Rosenau |
author_facet |
Marco Beaumont Paul Jusner Notburga Gierlinger Alistair W. T. King Antje Potthast Orlando J. Rojas Thomas Rosenau |
author_sort |
Marco Beaumont |
title |
Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water |
title_short |
Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water |
title_full |
Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water |
title_fullStr |
Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water |
title_full_unstemmed |
Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water |
title_sort |
unique reactivity of nanoporous cellulosic materials mediated by surface-confined water |
publisher |
Nature Portfolio |
publishDate |
2021 |
url |
https://doaj.org/article/1c87f8e079b5460aad80641c6577d9ce |
work_keys_str_mv |
AT marcobeaumont uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater AT pauljusner uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater AT notburgagierlinger uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater AT alistairwtking uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater AT antjepotthast uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater AT orlandojrojas uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater AT thomasrosenau uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater |
_version_ |
1718391237285773312 |