Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water

The efficiency of chemical reactions in biological systems is often connected to the properties of confined water, but the developments and applications of artificial mimicking systems are impeded by the complexity of the biological systems. Here, the authors show how surface bound water in nanoporo...

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Autores principales: Marco Beaumont, Paul Jusner, Notburga Gierlinger, Alistair W. T. King, Antje Potthast, Orlando J. Rojas, Thomas Rosenau
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2021
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Acceso en línea:https://doaj.org/article/1c87f8e079b5460aad80641c6577d9ce
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spelling oai:doaj.org-article:1c87f8e079b5460aad80641c6577d9ce2021-12-02T14:29:01ZUnique reactivity of nanoporous cellulosic materials mediated by surface-confined water10.1038/s41467-021-22682-32041-1723https://doaj.org/article/1c87f8e079b5460aad80641c6577d9ce2021-05-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22682-3https://doaj.org/toc/2041-1723The efficiency of chemical reactions in biological systems is often connected to the properties of confined water, but the developments and applications of artificial mimicking systems are impeded by the complexity of the biological systems. Here, the authors show how surface bound water in nanoporous cellulosic fibers can increase the reaction rate of surface acetylation reactions and enable regioselectivity of the reactionMarco BeaumontPaul JusnerNotburga GierlingerAlistair W. T. KingAntje PotthastOrlando J. RojasThomas RosenauNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Marco Beaumont
Paul Jusner
Notburga Gierlinger
Alistair W. T. King
Antje Potthast
Orlando J. Rojas
Thomas Rosenau
Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water
description The efficiency of chemical reactions in biological systems is often connected to the properties of confined water, but the developments and applications of artificial mimicking systems are impeded by the complexity of the biological systems. Here, the authors show how surface bound water in nanoporous cellulosic fibers can increase the reaction rate of surface acetylation reactions and enable regioselectivity of the reaction
format article
author Marco Beaumont
Paul Jusner
Notburga Gierlinger
Alistair W. T. King
Antje Potthast
Orlando J. Rojas
Thomas Rosenau
author_facet Marco Beaumont
Paul Jusner
Notburga Gierlinger
Alistair W. T. King
Antje Potthast
Orlando J. Rojas
Thomas Rosenau
author_sort Marco Beaumont
title Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water
title_short Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water
title_full Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water
title_fullStr Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water
title_full_unstemmed Unique reactivity of nanoporous cellulosic materials mediated by surface-confined water
title_sort unique reactivity of nanoporous cellulosic materials mediated by surface-confined water
publisher Nature Portfolio
publishDate 2021
url https://doaj.org/article/1c87f8e079b5460aad80641c6577d9ce
work_keys_str_mv AT marcobeaumont uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater
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AT alistairwtking uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater
AT antjepotthast uniquereactivityofnanoporouscellulosicmaterialsmediatedbysurfaceconfinedwater
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