Development and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders

The paper discusses various ways of activating phosphorus slags by introducing additives for the development of phosphorus slag binders (PSB), replacing cement. Considering that pseudowollastonite is the main mineral of phosphorus slags and without activating components does not possess the binding...

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Autores principales: Ultuar Mahambetova, Zatkali Estemesov, Bulbul Nuranbayeva, Pernekhan Sadykov, Orken Mamyrbayev, Dina Oralbekova
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Publicado: PC Technology Center 2021
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spelling oai:doaj.org-article:1d39d02ddb454d96b465821e8ac026a12021-11-04T14:09:04ZDevelopment and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders1729-37741729-406110.15587/1729-4061.2021.242814https://doaj.org/article/1d39d02ddb454d96b465821e8ac026a12021-10-01T00:00:00Zhttp://journals.uran.ua/eejet/article/view/242814https://doaj.org/toc/1729-3774https://doaj.org/toc/1729-4061The paper discusses various ways of activating phosphorus slags by introducing additives for the development of phosphorus slag binders (PSB), replacing cement. Considering that pseudowollastonite is the main mineral of phosphorus slags and without activating components does not possess the binding properties necessary for the production of building materials based on them, we used compositions of small amounts of sodium hydroxide with alkali metal salts, the anions of which form poorly soluble compounds with calcium. When choosing activating components, scarce alkaline additives were replaced by waste from chemical plants, which allows a passing solution of their practical use and environmental problems. The strength at a sodium hydroxide content of 1–4 % after curing of slag samples of various batches was in the range of 50.0–70.0 MPa. Samples of binders of normal hardening at the age of 28 days with a sodium hydroxide content of 0.5; 1.0, 2 and 4 % had the strength of 20.3; 35.4; 45.6; 55.8 MPa, respectively. The effect of the combined presence of alkali and salt is especially noticeable for small amounts of sodium hydroxide. Binders containing a composition of cement with salts under normal conditions and after curing showed a slightly lower strength than in an alkaline medium. With a constant cement content (4 %), the strength indicators increase with an increase in the proportion of the salt additive, reaching at 4 % its maximum value. The effect of the nature of activators on pH was determined. The data obtained indicate the advantages of using PSB and various industrial wastes with a low content of alkaline compounds in the productionUltuar MahambetovaZatkali EstemesovBulbul NuranbayevaPernekhan SadykovOrken MamyrbayevDina OralbekovaPC Technology Centerarticlephosphorus slagcementsodium hydroxidephosphorus slag bindersconstruction materialsTechnology (General)T1-995IndustryHD2321-4730.9ENRUUKEastern-European Journal of Enterprise Technologies, Vol 5, Iss 6 (113), Pp 54-61 (2021)
institution DOAJ
collection DOAJ
language EN
RU
UK
topic phosphorus slag
cement
sodium hydroxide
phosphorus slag binders
construction materials
Technology (General)
T1-995
Industry
HD2321-4730.9
spellingShingle phosphorus slag
cement
sodium hydroxide
phosphorus slag binders
construction materials
Technology (General)
T1-995
Industry
HD2321-4730.9
Ultuar Mahambetova
Zatkali Estemesov
Bulbul Nuranbayeva
Pernekhan Sadykov
Orken Mamyrbayev
Dina Oralbekova
Development and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders
description The paper discusses various ways of activating phosphorus slags by introducing additives for the development of phosphorus slag binders (PSB), replacing cement. Considering that pseudowollastonite is the main mineral of phosphorus slags and without activating components does not possess the binding properties necessary for the production of building materials based on them, we used compositions of small amounts of sodium hydroxide with alkali metal salts, the anions of which form poorly soluble compounds with calcium. When choosing activating components, scarce alkaline additives were replaced by waste from chemical plants, which allows a passing solution of their practical use and environmental problems. The strength at a sodium hydroxide content of 1–4 % after curing of slag samples of various batches was in the range of 50.0–70.0 MPa. Samples of binders of normal hardening at the age of 28 days with a sodium hydroxide content of 0.5; 1.0, 2 and 4 % had the strength of 20.3; 35.4; 45.6; 55.8 MPa, respectively. The effect of the combined presence of alkali and salt is especially noticeable for small amounts of sodium hydroxide. Binders containing a composition of cement with salts under normal conditions and after curing showed a slightly lower strength than in an alkaline medium. With a constant cement content (4 %), the strength indicators increase with an increase in the proportion of the salt additive, reaching at 4 % its maximum value. The effect of the nature of activators on pH was determined. The data obtained indicate the advantages of using PSB and various industrial wastes with a low content of alkaline compounds in the production
format article
author Ultuar Mahambetova
Zatkali Estemesov
Bulbul Nuranbayeva
Pernekhan Sadykov
Orken Mamyrbayev
Dina Oralbekova
author_facet Ultuar Mahambetova
Zatkali Estemesov
Bulbul Nuranbayeva
Pernekhan Sadykov
Orken Mamyrbayev
Dina Oralbekova
author_sort Ultuar Mahambetova
title Development and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders
title_short Development and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders
title_full Development and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders
title_fullStr Development and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders
title_full_unstemmed Development and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders
title_sort development and research of the influence of the composition and concentration of activators on the strength of phosphorus slag binders
publisher PC Technology Center
publishDate 2021
url https://doaj.org/article/1d39d02ddb454d96b465821e8ac026a1
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AT zatkaliestemesov developmentandresearchoftheinfluenceofthecompositionandconcentrationofactivatorsonthestrengthofphosphorusslagbinders
AT bulbulnuranbayeva developmentandresearchoftheinfluenceofthecompositionandconcentrationofactivatorsonthestrengthofphosphorusslagbinders
AT pernekhansadykov developmentandresearchoftheinfluenceofthecompositionandconcentrationofactivatorsonthestrengthofphosphorusslagbinders
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AT dinaoralbekova developmentandresearchoftheinfluenceofthecompositionandconcentrationofactivatorsonthestrengthofphosphorusslagbinders
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