Enhancing the catalytic activity of hydronium ions through constrained environments

Alcohol dehydration can be challenging in aqueous phase. Here the authors show that hydronium ions confined with zeolite pores catalyse alcohol dehydration at a significantly increased rate relative to aqueous phase hydronium ions, driven by an increased association between the ion and alcohol and a...

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Autores principales:	Yuanshuai Liu, Aleksei Vjunov, Hui Shi, Sebastian Eckstein, Donald M. Camaioni, Donghai Mei, Eszter Baráth, Johannes A. Lercher
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2017
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/1d416516117842aeba37a0e066579594
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id	oai:doaj.org-article:1d416516117842aeba37a0e066579594
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spelling	oai:doaj.org-article:1d416516117842aeba37a0e0665795942021-12-02T14:42:42ZEnhancing the catalytic activity of hydronium ions through constrained environments10.1038/ncomms141132041-1723https://doaj.org/article/1d416516117842aeba37a0e0665795942017-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms14113https://doaj.org/toc/2041-1723Alcohol dehydration can be challenging in aqueous phase. Here the authors show that hydronium ions confined with zeolite pores catalyse alcohol dehydration at a significantly increased rate relative to aqueous phase hydronium ions, driven by an increased association between the ion and alcohol and a greater entropy of activation.Yuanshuai LiuAleksei VjunovHui ShiSebastian EcksteinDonald M. CamaioniDonghai MeiEszter BaráthJohannes A. LercherNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-8 (2017)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yuanshuai Liu Aleksei Vjunov Hui Shi Sebastian Eckstein Donald M. Camaioni Donghai Mei Eszter Baráth Johannes A. Lercher Enhancing the catalytic activity of hydronium ions through constrained environments
description	Alcohol dehydration can be challenging in aqueous phase. Here the authors show that hydronium ions confined with zeolite pores catalyse alcohol dehydration at a significantly increased rate relative to aqueous phase hydronium ions, driven by an increased association between the ion and alcohol and a greater entropy of activation.
format	article
author	Yuanshuai Liu Aleksei Vjunov Hui Shi Sebastian Eckstein Donald M. Camaioni Donghai Mei Eszter Baráth Johannes A. Lercher
author_facet	Yuanshuai Liu Aleksei Vjunov Hui Shi Sebastian Eckstein Donald M. Camaioni Donghai Mei Eszter Baráth Johannes A. Lercher
author_sort	Yuanshuai Liu
title	Enhancing the catalytic activity of hydronium ions through constrained environments
title_short	Enhancing the catalytic activity of hydronium ions through constrained environments
title_full	Enhancing the catalytic activity of hydronium ions through constrained environments
title_fullStr	Enhancing the catalytic activity of hydronium ions through constrained environments
title_full_unstemmed	Enhancing the catalytic activity of hydronium ions through constrained environments
title_sort	enhancing the catalytic activity of hydronium ions through constrained environments
publisher	Nature Portfolio
publishDate	2017
url	https://doaj.org/article/1d416516117842aeba37a0e066579594
work_keys_str_mv	AT yuanshuailiu enhancingthecatalyticactivityofhydroniumionsthroughconstrainedenvironments AT alekseivjunov enhancingthecatalyticactivityofhydroniumionsthroughconstrainedenvironments AT huishi enhancingthecatalyticactivityofhydroniumionsthroughconstrainedenvironments AT sebastianeckstein enhancingthecatalyticactivityofhydroniumionsthroughconstrainedenvironments AT donaldmcamaioni enhancingthecatalyticactivityofhydroniumionsthroughconstrainedenvironments AT donghaimei enhancingthecatalyticactivityofhydroniumionsthroughconstrainedenvironments AT eszterbarath enhancingthecatalyticactivityofhydroniumionsthroughconstrainedenvironments AT johannesalercher enhancingthecatalyticactivityofhydroniumionsthroughconstrainedenvironments
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Enhancing the catalytic activity of hydronium ions through constrained environments

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