Direct conversion of methane to formaldehyde and CO on B2O3 catalysts

Partial oxidation of methane to value-added C1 products remains challenging due to the favorable formation of fully-oxidized CO2. Here, the authors show supported B2O3 catalysts with tri-coordinated BO3 units as the active site are highly selective in oxidizing methane to HCHO and CO.

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Auteurs principaux: Jinshu Tian, Jiangqiao Tan, Zhaoxia Zhang, Peijie Han, Min Yin, Shaolong Wan, Jingdong Lin, Shuai Wang, Yong Wang
Format: article
Langue:EN
Publié: Nature Portfolio 2020
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Accès en ligne:https://doaj.org/article/1d4300e913514c6da2cb9bda82ae0d10
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Résumé:Partial oxidation of methane to value-added C1 products remains challenging due to the favorable formation of fully-oxidized CO2. Here, the authors show supported B2O3 catalysts with tri-coordinated BO3 units as the active site are highly selective in oxidizing methane to HCHO and CO.