Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes

Classical Suzuki-Miyaura couplings require wasteful electrophilic coupling partners and an exogenous base often engaging in side-reactions. Here, the authors report an alternative Suzuki-type synthesis of biaryls, involving the base-free nickel-catalyzed deformylative coupling of aldehydes with orga...

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Autores principales:	Lin Guo, Watchara Srimontree, Chen Zhu, Bholanath Maity, Xiangqian Liu, Luigi Cavallo, Magnus Rueping
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/1dd80129277045a59ff2d6711c078b3f
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spelling	oai:doaj.org-article:1dd80129277045a59ff2d6711c078b3f2021-12-02T16:57:44ZNickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes10.1038/s41467-019-09766-x2041-1723https://doaj.org/article/1dd80129277045a59ff2d6711c078b3f2019-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-09766-xhttps://doaj.org/toc/2041-1723Classical Suzuki-Miyaura couplings require wasteful electrophilic coupling partners and an exogenous base often engaging in side-reactions. Here, the authors report an alternative Suzuki-type synthesis of biaryls, involving the base-free nickel-catalyzed deformylative coupling of aldehydes with organoboron reagents.Lin GuoWatchara SrimontreeChen ZhuBholanath MaityXiangqian LiuLuigi CavalloMagnus RuepingNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-6 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Lin Guo Watchara Srimontree Chen Zhu Bholanath Maity Xiangqian Liu Luigi Cavallo Magnus Rueping Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
description	Classical Suzuki-Miyaura couplings require wasteful electrophilic coupling partners and an exogenous base often engaging in side-reactions. Here, the authors report an alternative Suzuki-type synthesis of biaryls, involving the base-free nickel-catalyzed deformylative coupling of aldehydes with organoboron reagents.
format	article
author	Lin Guo Watchara Srimontree Chen Zhu Bholanath Maity Xiangqian Liu Luigi Cavallo Magnus Rueping
author_facet	Lin Guo Watchara Srimontree Chen Zhu Bholanath Maity Xiangqian Liu Luigi Cavallo Magnus Rueping
author_sort	Lin Guo
title	Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
title_short	Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
title_full	Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
title_fullStr	Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
title_full_unstemmed	Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes
title_sort	nickel-catalyzed suzuki–miyaura cross-couplings of aldehydes
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/1dd80129277045a59ff2d6711c078b3f
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Nickel-catalyzed Suzuki–Miyaura cross-couplings of aldehydes

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