Ru(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses

Selectivity in carbene insertion reactions promoted by Ru(II)porphyrinates is achieved only upon careful control of substrate stoichiometry. Here, the authors demonstrate that endotopic catalysis and formation of mechanical bonds enables carbene insertions to occur selectively and in quantitative yi...

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Autores principales:	Liniquer A. Fontana, Marlon P. Almeida, Arthur F. P. Alcântara, Vitor H. Rigolin, Marcos A. Ribeiro, Wdeson P. Barros, Jackson D. Megiatto
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/1df2b4e426944f1dbd7ca8dcac32122d
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spelling	oai:doaj.org-article:1df2b4e426944f1dbd7ca8dcac32122d2021-12-02T13:24:15ZRu(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses10.1038/s41467-020-20046-x2041-1723https://doaj.org/article/1df2b4e426944f1dbd7ca8dcac32122d2020-12-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20046-xhttps://doaj.org/toc/2041-1723Selectivity in carbene insertion reactions promoted by Ru(II)porphyrinates is achieved only upon careful control of substrate stoichiometry. Here, the authors demonstrate that endotopic catalysis and formation of mechanical bonds enables carbene insertions to occur selectively and in quantitative yield regardless of substrate stoichiometry.Liniquer A. FontanaMarlon P. AlmeidaArthur F. P. AlcântaraVitor H. RigolinMarcos A. RibeiroWdeson P. BarrosJackson D. MegiattoNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-10 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Liniquer A. Fontana Marlon P. Almeida Arthur F. P. Alcântara Vitor H. Rigolin Marcos A. Ribeiro Wdeson P. Barros Jackson D. Megiatto Ru(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses
description	Selectivity in carbene insertion reactions promoted by Ru(II)porphyrinates is achieved only upon careful control of substrate stoichiometry. Here, the authors demonstrate that endotopic catalysis and formation of mechanical bonds enables carbene insertions to occur selectively and in quantitative yield regardless of substrate stoichiometry.
format	article
author	Liniquer A. Fontana Marlon P. Almeida Arthur F. P. Alcântara Vitor H. Rigolin Marcos A. Ribeiro Wdeson P. Barros Jackson D. Megiatto
author_facet	Liniquer A. Fontana Marlon P. Almeida Arthur F. P. Alcântara Vitor H. Rigolin Marcos A. Ribeiro Wdeson P. Barros Jackson D. Megiatto
author_sort	Liniquer A. Fontana
title	Ru(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses
title_short	Ru(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses
title_full	Ru(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses
title_fullStr	Ru(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses
title_full_unstemmed	Ru(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses
title_sort	ru(ii)porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/1df2b4e426944f1dbd7ca8dcac32122d
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Ru(II)Porphyrinate-based molecular nanoreactor for carbene insertion reactions and quantitative formation of rotaxanes by active-metal-template syntheses

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