Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design

The development of highly effective Earth-abundant catalysts for C(sp2)-N cross-coupling represents an on-going challenge in synthetic chemistry. Here, the authors report a nickel complex containing a bisphosphine ancillary ligand allowing room-temperature couplings of amines and ammonia with a rang...

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Autores principales:	Christopher M. Lavoie, Preston M. MacQueen, Nicolas L. Rotta-Loria, Ryan S. Sawatzky, Andrey Borzenko, Alicia J. Chisholm, Breanna K. V. Hargreaves, Robert McDonald, Michael J. Ferguson, Mark Stradiotto
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/1ea983677eed44938be8c3fecf2ad18a
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id	oai:doaj.org-article:1ea983677eed44938be8c3fecf2ad18a
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spelling	oai:doaj.org-article:1ea983677eed44938be8c3fecf2ad18a2021-12-02T16:49:58ZChallenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design10.1038/ncomms110732041-1723https://doaj.org/article/1ea983677eed44938be8c3fecf2ad18a2016-03-01T00:00:00Zhttps://doi.org/10.1038/ncomms11073https://doaj.org/toc/2041-1723The development of highly effective Earth-abundant catalysts for C(sp2)-N cross-coupling represents an on-going challenge in synthetic chemistry. Here, the authors report a nickel complex containing a bisphosphine ancillary ligand allowing room-temperature couplings of amines and ammonia with a range of electrophiles.Christopher M. LavoiePreston M. MacQueenNicolas L. Rotta-LoriaRyan S. SawatzkyAndrey BorzenkoAlicia J. ChisholmBreanna K. V. HargreavesRobert McDonaldMichael J. FergusonMark StradiottoNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-11 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Christopher M. Lavoie Preston M. MacQueen Nicolas L. Rotta-Loria Ryan S. Sawatzky Andrey Borzenko Alicia J. Chisholm Breanna K. V. Hargreaves Robert McDonald Michael J. Ferguson Mark Stradiotto Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design
description	The development of highly effective Earth-abundant catalysts for C(sp2)-N cross-coupling represents an on-going challenge in synthetic chemistry. Here, the authors report a nickel complex containing a bisphosphine ancillary ligand allowing room-temperature couplings of amines and ammonia with a range of electrophiles.
format	article
author	Christopher M. Lavoie Preston M. MacQueen Nicolas L. Rotta-Loria Ryan S. Sawatzky Andrey Borzenko Alicia J. Chisholm Breanna K. V. Hargreaves Robert McDonald Michael J. Ferguson Mark Stradiotto
author_facet	Christopher M. Lavoie Preston M. MacQueen Nicolas L. Rotta-Loria Ryan S. Sawatzky Andrey Borzenko Alicia J. Chisholm Breanna K. V. Hargreaves Robert McDonald Michael J. Ferguson Mark Stradiotto
author_sort	Christopher M. Lavoie
title	Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design
title_short	Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design
title_full	Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design
title_fullStr	Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design
title_full_unstemmed	Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design
title_sort	challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/1ea983677eed44938be8c3fecf2ad18a
work_keys_str_mv	AT christophermlavoie challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign AT prestonmmacqueen challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign AT nicolaslrottaloria challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign AT ryanssawatzky challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign AT andreyborzenko challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign AT aliciajchisholm challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign AT breannakvhargreaves challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign AT robertmcdonald challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign AT michaeljferguson challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign AT markstradiotto challengingnickelcatalysedaminearylationsenabledbytailoredancillaryliganddesign
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Challenging nickel-catalysed amine arylations enabled by tailored ancillary ligand design

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