Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation

Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation

C–H activations and hydroaminations are useful synthetic procedures for building up complex, functional molecules. Here, the authors report a single catalyst capable of performing tandem C–H activation and hydroamination, giving access to N-heterocycles via the [4+2] annulation of aromatic imines an...

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Autores principales: Rajith S. Manan, Pinjing Zhao
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2016
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Acceso en línea:https://doaj.org/article/1eadc2309b74490a95a6d8f34cbf5eb0
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spelling oai:doaj.org-article:1eadc2309b74490a95a6d8f34cbf5eb02021-12-02T15:34:50ZMerging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation10.1038/ncomms115062041-1723https://doaj.org/article/1eadc2309b74490a95a6d8f34cbf5eb02016-06-01T00:00:00Zhttps://doi.org/10.1038/ncomms11506https://doaj.org/toc/2041-1723C–H activations and hydroaminations are useful synthetic procedures for building up complex, functional molecules. Here, the authors report a single catalyst capable of performing tandem C–H activation and hydroamination, giving access to N-heterocycles via the [4+2] annulation of aromatic imines and alkynes.Rajith S. MananPinjing ZhaoNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-11 (2016)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Rajith S. Manan
Pinjing Zhao
Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation
description C–H activations and hydroaminations are useful synthetic procedures for building up complex, functional molecules. Here, the authors report a single catalyst capable of performing tandem C–H activation and hydroamination, giving access to N-heterocycles via the [4+2] annulation of aromatic imines and alkynes.
format article
author Rajith S. Manan
Pinjing Zhao
author_facet Rajith S. Manan
Pinjing Zhao
author_sort Rajith S. Manan
title Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation
title_short Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation
title_full Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation
title_fullStr Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation
title_full_unstemmed Merging rhodium-catalysed C–H activation and hydroamination in a highly selective [4+2] imine/alkyne annulation
title_sort merging rhodium-catalysed c–h activation and hydroamination in a highly selective [4+2] imine/alkyne annulation
publisher Nature Portfolio
publishDate 2016
url https://doaj.org/article/1eadc2309b74490a95a6d8f34cbf5eb0
work_keys_str_mv AT rajithsmanan mergingrhodiumcatalysedchactivationandhydroaminationinahighlyselective42iminealkyneannulation
AT pinjingzhao mergingrhodiumcatalysedchactivationandhydroaminationinahighlyselective42iminealkyneannulation
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