Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene

Full utilization of ZSM-5 shape-selectivity is restricted by crystal external surface acid sites and co-existence of two different sized channels. Here, the authors synthesize reverse Al zoned ZSM-5 with sinusoidal channel preferentially opened to its inert external surface to achieve 99.3% p-xylene...

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Autores principales: Chuanfu Wang, Lei Zhang, Xin Huang, Yufei Zhu, Gang (Kevin) Li, Qinfen Gu, Jingyun Chen, Linge Ma, Xiujie Li, Qihua He, Junbo Xu, Qi Sun, Chuqiao Song, Mi Peng, Junliang Sun, Ding Ma
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Publicado: Nature Portfolio 2019
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Acceso en línea:https://doaj.org/article/1ec4943f46554dc89c8ddcaae263bf53
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spelling oai:doaj.org-article:1ec4943f46554dc89c8ddcaae263bf532021-12-02T16:57:45ZMaximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene10.1038/s41467-019-12285-42041-1723https://doaj.org/article/1ec4943f46554dc89c8ddcaae263bf532019-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12285-4https://doaj.org/toc/2041-1723Full utilization of ZSM-5 shape-selectivity is restricted by crystal external surface acid sites and co-existence of two different sized channels. Here, the authors synthesize reverse Al zoned ZSM-5 with sinusoidal channel preferentially opened to its inert external surface to achieve 99.3% p-xylene selectivity.Chuanfu WangLei ZhangXin HuangYufei ZhuGang (Kevin) LiQinfen GuJingyun ChenLinge MaXiujie LiQihua HeJunbo XuQi SunChuqiao SongMi PengJunliang SunDing MaNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-8 (2019)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Chuanfu Wang
Lei Zhang
Xin Huang
Yufei Zhu
Gang (Kevin) Li
Qinfen Gu
Jingyun Chen
Linge Ma
Xiujie Li
Qihua He
Junbo Xu
Qi Sun
Chuqiao Song
Mi Peng
Junliang Sun
Ding Ma
Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
description Full utilization of ZSM-5 shape-selectivity is restricted by crystal external surface acid sites and co-existence of two different sized channels. Here, the authors synthesize reverse Al zoned ZSM-5 with sinusoidal channel preferentially opened to its inert external surface to achieve 99.3% p-xylene selectivity.
format article
author Chuanfu Wang
Lei Zhang
Xin Huang
Yufei Zhu
Gang (Kevin) Li
Qinfen Gu
Jingyun Chen
Linge Ma
Xiujie Li
Qihua He
Junbo Xu
Qi Sun
Chuqiao Song
Mi Peng
Junliang Sun
Ding Ma
author_facet Chuanfu Wang
Lei Zhang
Xin Huang
Yufei Zhu
Gang (Kevin) Li
Qinfen Gu
Jingyun Chen
Linge Ma
Xiujie Li
Qihua He
Junbo Xu
Qi Sun
Chuqiao Song
Mi Peng
Junliang Sun
Ding Ma
author_sort Chuanfu Wang
title Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_short Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_full Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_fullStr Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_full_unstemmed Maximizing sinusoidal channels of HZSM-5 for high shape-selectivity to p-xylene
title_sort maximizing sinusoidal channels of hzsm-5 for high shape-selectivity to p-xylene
publisher Nature Portfolio
publishDate 2019
url https://doaj.org/article/1ec4943f46554dc89c8ddcaae263bf53
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