Boron-mediated directed aromatic C–H hydroxylation

Transition metal-catalysed C–H hydroxylation is one of the most notable synthetic advances to access alcohols and phenols. Here, the authors report a metal-free, mild C–H hydroxylation of (hetero)arenes via boron-mediated chelation.

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Detalles Bibliográficos
Autores principales: Jiahang Lv, Binlin Zhao, Yu Yuan, Ying Han, Zhuangzhi Shi
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/1ed1e283e9fb432eb928f81f9c819f25
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Sumario:Transition metal-catalysed C–H hydroxylation is one of the most notable synthetic advances to access alcohols and phenols. Here, the authors report a metal-free, mild C–H hydroxylation of (hetero)arenes via boron-mediated chelation.