Boron-mediated directed aromatic C–H hydroxylation

Boron-mediated directed aromatic C–H hydroxylation

Transition metal-catalysed C–H hydroxylation is one of the most notable synthetic advances to access alcohols and phenols. Here, the authors report a metal-free, mild C–H hydroxylation of (hetero)arenes via boron-mediated chelation.

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Autores principales: Jiahang Lv, Binlin Zhao, Yu Yuan, Ying Han, Zhuangzhi Shi
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
Materias:
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Q
Acceso en línea:https://doaj.org/article/1ed1e283e9fb432eb928f81f9c819f25
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spelling oai:doaj.org-article:1ed1e283e9fb432eb928f81f9c819f252021-12-02T15:39:16ZBoron-mediated directed aromatic C–H hydroxylation10.1038/s41467-020-15207-x2041-1723https://doaj.org/article/1ed1e283e9fb432eb928f81f9c819f252020-03-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-15207-xhttps://doaj.org/toc/2041-1723Transition metal-catalysed C–H hydroxylation is one of the most notable synthetic advances to access alcohols and phenols. Here, the authors report a metal-free, mild C–H hydroxylation of (hetero)arenes via boron-mediated chelation.Jiahang LvBinlin ZhaoYu YuanYing HanZhuangzhi ShiNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Jiahang Lv
Binlin Zhao
Yu Yuan
Ying Han
Zhuangzhi Shi
Boron-mediated directed aromatic C–H hydroxylation
description Transition metal-catalysed C–H hydroxylation is one of the most notable synthetic advances to access alcohols and phenols. Here, the authors report a metal-free, mild C–H hydroxylation of (hetero)arenes via boron-mediated chelation.
format article
author Jiahang Lv
Binlin Zhao
Yu Yuan
Ying Han
Zhuangzhi Shi
author_facet Jiahang Lv
Binlin Zhao
Yu Yuan
Ying Han
Zhuangzhi Shi
author_sort Jiahang Lv
title Boron-mediated directed aromatic C–H hydroxylation
title_short Boron-mediated directed aromatic C–H hydroxylation
title_full Boron-mediated directed aromatic C–H hydroxylation
title_fullStr Boron-mediated directed aromatic C–H hydroxylation
title_full_unstemmed Boron-mediated directed aromatic C–H hydroxylation
title_sort boron-mediated directed aromatic c–h hydroxylation
publisher Nature Portfolio
publishDate 2020
url https://doaj.org/article/1ed1e283e9fb432eb928f81f9c819f25
work_keys_str_mv AT jiahanglv boronmediateddirectedaromaticchhydroxylation
AT binlinzhao boronmediateddirectedaromaticchhydroxylation
AT yuyuan boronmediateddirectedaromaticchhydroxylation
AT yinghan boronmediateddirectedaromaticchhydroxylation
AT zhuangzhishi boronmediateddirectedaromaticchhydroxylation
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