Electrochemical surface passivation of LiCoO2 particles at ultrahigh voltage and its applications in lithium-based batteries

LiCoO2 is a cathode material widely used in lithium-ion batteries but suffers from solubilization of cobalt and structural disorder when the voltage is increased to release more capacity. Here the authors show a ternary Li, Al and F-modified LiCoO2 and battery cells with stable cycling behavior over...

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Autores principales: Jiawei Qian, Lei Liu, Jixiang Yang, Siyuan Li, Xiao Wang, Houlong L. Zhuang, Yingying Lu
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2018
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Acceso en línea:https://doaj.org/article/1f3dea4524af4f96933a114ebf30b0f0
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Sumario:LiCoO2 is a cathode material widely used in lithium-ion batteries but suffers from solubilization of cobalt and structural disorder when the voltage is increased to release more capacity. Here the authors show a ternary Li, Al and F-modified LiCoO2 and battery cells with stable cycling behavior over 4.55 V.