Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction
Nitrogen-doped carbon materials with atomically dispersed iron or cobalt are promising for catalytic use. Here, the authors show that cobalt moieties have a higher redox potential, bind oxygen more weakly and are less active toward oxygen reduction than their iron counterpart, despite similar coordi...
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Nature Portfolio
2017
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oai:doaj.org-article:1f54d903097e4f9b80a2211841b501d22021-12-02T15:38:32ZIdentification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction10.1038/s41467-017-01100-72041-1723https://doaj.org/article/1f54d903097e4f9b80a2211841b501d22017-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-01100-7https://doaj.org/toc/2041-1723Nitrogen-doped carbon materials with atomically dispersed iron or cobalt are promising for catalytic use. Here, the authors show that cobalt moieties have a higher redox potential, bind oxygen more weakly and are less active toward oxygen reduction than their iron counterpart, despite similar coordination.Andrea ZitoloNastaran Ranjbar-SahraieTzonka MinevaJingkun LiQingying JiaSerban StamatinGeorge F. HarringtonStephen Mathew LythPetr KrtilSanjeev MukerjeeEmiliano FondaFrédéric JaouenNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-11 (2017) |
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Science Q |
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Science Q Andrea Zitolo Nastaran Ranjbar-Sahraie Tzonka Mineva Jingkun Li Qingying Jia Serban Stamatin George F. Harrington Stephen Mathew Lyth Petr Krtil Sanjeev Mukerjee Emiliano Fonda Frédéric Jaouen Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction |
description |
Nitrogen-doped carbon materials with atomically dispersed iron or cobalt are promising for catalytic use. Here, the authors show that cobalt moieties have a higher redox potential, bind oxygen more weakly and are less active toward oxygen reduction than their iron counterpart, despite similar coordination. |
format |
article |
author |
Andrea Zitolo Nastaran Ranjbar-Sahraie Tzonka Mineva Jingkun Li Qingying Jia Serban Stamatin George F. Harrington Stephen Mathew Lyth Petr Krtil Sanjeev Mukerjee Emiliano Fonda Frédéric Jaouen |
author_facet |
Andrea Zitolo Nastaran Ranjbar-Sahraie Tzonka Mineva Jingkun Li Qingying Jia Serban Stamatin George F. Harrington Stephen Mathew Lyth Petr Krtil Sanjeev Mukerjee Emiliano Fonda Frédéric Jaouen |
author_sort |
Andrea Zitolo |
title |
Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction |
title_short |
Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction |
title_full |
Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction |
title_fullStr |
Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction |
title_full_unstemmed |
Identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction |
title_sort |
identification of catalytic sites in cobalt-nitrogen-carbon materials for the oxygen reduction reaction |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/1f54d903097e4f9b80a2211841b501d2 |
work_keys_str_mv |
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1718386158249967616 |