The neutron diffraction studies of a crystal structure of nafe(wxmo1-xo4)2 (x = 0.5; 0.75) at low temperature
The crystal structure of the double tungstates NaFe(W0.5Mo0.5O4)2 and NaFe(W0.75Mo0.25O4)2 has been studied by means of a neutron diffraction method in temperature range 5-24 K. No evidence for long range magnetic order was found in both compounds down to 5 K. The unit cell parameters, atomic coordi...
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D.Ghitu Institute of Electronic Engineering and Nanotechnologies
2016
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oai:doaj.org-article:2006743eb35f472b92087fa63dae926d2021-11-21T11:57:11ZThe neutron diffraction studies of a crystal structure of nafe(wxmo1-xo4)2 (x = 0.5; 0.75) at low temperature538.9+544.22537-63651810-648Xhttps://doaj.org/article/2006743eb35f472b92087fa63dae926d2016-12-01T00:00:00Zhttps://mjps.nanotech.md/archive/2016/article/51533https://doaj.org/toc/1810-648Xhttps://doaj.org/toc/2537-6365The crystal structure of the double tungstates NaFe(W0.5Mo0.5O4)2 and NaFe(W0.75Mo0.25O4)2 has been studied by means of a neutron diffraction method in temperature range 5-24 K. No evidence for long range magnetic order was found in both compounds down to 5 K. The unit cell parameters, atomic coordinates, bond lengths and angles for the studied compounds have been obtained. An absence of magnetic ordering is explained by reduction of super-exchange coupling due to a disordering of a Fe-O-O-Fe trapeze-like crystal unit. Thanh, V.Cozlenco, DenisSangaa, D.Kicianov, SergheiLukin, EvgheniiKhiem, L.Nyam-Ochir, L.Gerelmaa, O.Savenco, BD.Ghitu Institute of Electronic Engineering and NanotechnologiesarticlePhysicsQC1-999ElectronicsTK7800-8360ENMoldavian Journal of the Physical Sciences, Vol 15, Iss 3-4, Pp 119-124 (2016) |
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Physics QC1-999 Electronics TK7800-8360 Thanh, V. Cozlenco, Denis Sangaa, D. Kicianov, Serghei Lukin, Evghenii Khiem, L. Nyam-Ochir, L. Gerelmaa, O. Savenco, B The neutron diffraction studies of a crystal structure of nafe(wxmo1-xo4)2 (x = 0.5; 0.75) at low temperature |
description |
The crystal structure of the double tungstates NaFe(W0.5Mo0.5O4)2 and NaFe(W0.75Mo0.25O4)2 has been studied by means of a neutron diffraction method in temperature range 5-24 K. No evidence for long range magnetic order was found in both compounds down to 5 K. The unit cell parameters, atomic coordinates, bond lengths and angles for the studied compounds have been obtained. An absence of magnetic ordering is explained by reduction of super-exchange coupling due to a disordering of a Fe-O-O-Fe trapeze-like crystal unit. |
format |
article |
author |
Thanh, V. Cozlenco, Denis Sangaa, D. Kicianov, Serghei Lukin, Evghenii Khiem, L. Nyam-Ochir, L. Gerelmaa, O. Savenco, B |
author_facet |
Thanh, V. Cozlenco, Denis Sangaa, D. Kicianov, Serghei Lukin, Evghenii Khiem, L. Nyam-Ochir, L. Gerelmaa, O. Savenco, B |
author_sort |
Thanh, V. |
title |
The neutron diffraction studies of a crystal structure of nafe(wxmo1-xo4)2 (x = 0.5; 0.75) at low temperature |
title_short |
The neutron diffraction studies of a crystal structure of nafe(wxmo1-xo4)2 (x = 0.5; 0.75) at low temperature |
title_full |
The neutron diffraction studies of a crystal structure of nafe(wxmo1-xo4)2 (x = 0.5; 0.75) at low temperature |
title_fullStr |
The neutron diffraction studies of a crystal structure of nafe(wxmo1-xo4)2 (x = 0.5; 0.75) at low temperature |
title_full_unstemmed |
The neutron diffraction studies of a crystal structure of nafe(wxmo1-xo4)2 (x = 0.5; 0.75) at low temperature |
title_sort |
neutron diffraction studies of a crystal structure of nafe(wxmo1-xo4)2 (x = 0.5; 0.75) at low temperature |
publisher |
D.Ghitu Institute of Electronic Engineering and Nanotechnologies |
publishDate |
2016 |
url |
https://doaj.org/article/2006743eb35f472b92087fa63dae926d |
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