Observation of the geometric phase effect in the H+HD→H2+D reaction below the conical intersection

The geometric phase effect associated with a conical intersection between the ground and first excited electronic state has been predicted in the H3 system below the conical intersection energy. The authors, by a crossed molecular beam technique and quantum dynamic calculations, provide experimental...

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Autores principales: Daofu Yuan, Yin Huang, Wentao Chen, Hailin Zhao, Shengrui Yu, Chang Luo, Yuxin Tan, Siwen Wang, Xingan Wang, Zhigang Sun, Xueming Yang
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2020
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Acceso en línea:https://doaj.org/article/2045d474874846e6a42ffd08eff5c2ca
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Sumario:The geometric phase effect associated with a conical intersection between the ground and first excited electronic state has been predicted in the H3 system below the conical intersection energy. The authors, by a crossed molecular beam technique and quantum dynamic calculations, provide experimental evidence and insight into its origin.