Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition

Abstract We report herein a visible light sensitizer-catalyzed aerobic oxidation of thioethers, affording sulfoxides in good to excellent yields. The loading of the catalyst was as low as 0.1 mol%. The selectivity was excellent. Mechanism studies showed both singlet oxygen and superoxide radical ani...

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Autores principales:	Cong Ye, Yanbin Zhang, Aishun Ding, Yong Hu, Hao Guo
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2018
Materias:	Medicine R Science Q
Acceso en línea:	https://doaj.org/article/2055aef7e7aa404c9b14077e67bfb34b
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spelling	oai:doaj.org-article:2055aef7e7aa404c9b14077e67bfb34b2021-12-02T15:08:25ZVisible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition10.1038/s41598-018-20631-72045-2322https://doaj.org/article/2055aef7e7aa404c9b14077e67bfb34b2018-02-01T00:00:00Zhttps://doi.org/10.1038/s41598-018-20631-7https://doaj.org/toc/2045-2322Abstract We report herein a visible light sensitizer-catalyzed aerobic oxidation of thioethers, affording sulfoxides in good to excellent yields. The loading of the catalyst was as low as 0.1 mol%. The selectivity was excellent. Mechanism studies showed both singlet oxygen and superoxide radical anion were likely involved in this transformation.Cong YeYanbin ZhangAishun DingYong HuHao GuoNature PortfolioarticleMedicineRScienceQENScientific Reports, Vol 8, Iss 1, Pp 1-6 (2018)
institution	DOAJ
collection	DOAJ
language	EN
topic	Medicine R Science Q
spellingShingle	Medicine R Science Q Cong Ye Yanbin Zhang Aishun Ding Yong Hu Hao Guo Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition
description	Abstract We report herein a visible light sensitizer-catalyzed aerobic oxidation of thioethers, affording sulfoxides in good to excellent yields. The loading of the catalyst was as low as 0.1 mol%. The selectivity was excellent. Mechanism studies showed both singlet oxygen and superoxide radical anion were likely involved in this transformation.
format	article
author	Cong Ye Yanbin Zhang Aishun Ding Yong Hu Hao Guo
author_facet	Cong Ye Yanbin Zhang Aishun Ding Yong Hu Hao Guo
author_sort	Cong Ye
title	Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition
title_short	Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition
title_full	Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition
title_fullStr	Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition
title_full_unstemmed	Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition
title_sort	visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition
publisher	Nature Portfolio
publishDate	2018
url	https://doaj.org/article/2055aef7e7aa404c9b14077e67bfb34b
work_keys_str_mv	AT congye visiblelightsensitizercatalyzedhighlyselectivephotooxidationfromthioethersintosulfoxidesunderaerobiccondition AT yanbinzhang visiblelightsensitizercatalyzedhighlyselectivephotooxidationfromthioethersintosulfoxidesunderaerobiccondition AT aishunding visiblelightsensitizercatalyzedhighlyselectivephotooxidationfromthioethersintosulfoxidesunderaerobiccondition AT yonghu visiblelightsensitizercatalyzedhighlyselectivephotooxidationfromthioethersintosulfoxidesunderaerobiccondition AT haoguo visiblelightsensitizercatalyzedhighlyselectivephotooxidationfromthioethersintosulfoxidesunderaerobiccondition
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Visible light sensitizer-catalyzed highly selective photo oxidation from thioethers into sulfoxides under aerobic condition

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