Benzylic C−H acylation by cooperative NHC and photoredox catalysis

Direct acylation of sp3 C−H bonds in complex organic molecules is not well established compared to that of sp2 C−H bonds. Here, the authors report the combination of N-heterocyclic carbene (NHC) and photoredox catalysis for the direct and site-selective acylation of benzylic C−H bonds.

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Autores principales:	Qing-Yuan Meng, Lena Lezius, Armido Studer
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2021
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/206c91186263457f895c2e04f24090e8
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spelling	oai:doaj.org-article:206c91186263457f895c2e04f24090e82021-12-02T18:15:29ZBenzylic C−H acylation by cooperative NHC and photoredox catalysis10.1038/s41467-021-22292-z2041-1723https://doaj.org/article/206c91186263457f895c2e04f24090e82021-04-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-22292-zhttps://doaj.org/toc/2041-1723Direct acylation of sp3 C−H bonds in complex organic molecules is not well established compared to that of sp2 C−H bonds. Here, the authors report the combination of N-heterocyclic carbene (NHC) and photoredox catalysis for the direct and site-selective acylation of benzylic C−H bonds.Qing-Yuan MengLena LeziusArmido StuderNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Qing-Yuan Meng Lena Lezius Armido Studer Benzylic C−H acylation by cooperative NHC and photoredox catalysis
description	Direct acylation of sp3 C−H bonds in complex organic molecules is not well established compared to that of sp2 C−H bonds. Here, the authors report the combination of N-heterocyclic carbene (NHC) and photoredox catalysis for the direct and site-selective acylation of benzylic C−H bonds.
format	article
author	Qing-Yuan Meng Lena Lezius Armido Studer
author_facet	Qing-Yuan Meng Lena Lezius Armido Studer
author_sort	Qing-Yuan Meng
title	Benzylic C−H acylation by cooperative NHC and photoredox catalysis
title_short	Benzylic C−H acylation by cooperative NHC and photoredox catalysis
title_full	Benzylic C−H acylation by cooperative NHC and photoredox catalysis
title_fullStr	Benzylic C−H acylation by cooperative NHC and photoredox catalysis
title_full_unstemmed	Benzylic C−H acylation by cooperative NHC and photoredox catalysis
title_sort	benzylic c−h acylation by cooperative nhc and photoredox catalysis
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/206c91186263457f895c2e04f24090e8
work_keys_str_mv	AT qingyuanmeng benzylicchacylationbycooperativenhcandphotoredoxcatalysis AT lenalezius benzylicchacylationbycooperativenhcandphotoredoxcatalysis AT armidostuder benzylicchacylationbycooperativenhcandphotoredoxcatalysis
_version_	1718378381033078784

Benzylic C−H acylation by cooperative NHC and photoredox catalysis

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