Organotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n

Crystallization of [(Ph3Sn)2SeO4] ⋅ 1.5H2O in methanol leads to the formation of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n (1) which constitutes a new specimen of organotin(IV) selenate derivatives. In the solid state, complex 1 is arranged in polymeric zig-zag chains, composed of alternating Ph3Sn and SeO4 groups....

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Autores principales:	Diallo Waly, Cattey Hélène, Plasseraud Laurent
Formato:	article
Lenguaje:	EN
Publicado:	De Gruyter 2021
Materias:	organotin(iv) selenium sn-o-se moiety crystal structure inorganic chain Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/208c9d1615ef4cb29ed12b5b21cbee5d
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spelling	oai:doaj.org-article:208c9d1615ef4cb29ed12b5b21cbee5d2021-12-05T14:10:56ZOrganotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n0792-12412191-021910.1515/mgmc-2021-0023https://doaj.org/article/208c9d1615ef4cb29ed12b5b21cbee5d2021-07-01T00:00:00Zhttps://doi.org/10.1515/mgmc-2021-0023https://doaj.org/toc/0792-1241https://doaj.org/toc/2191-0219Crystallization of [(Ph3Sn)2SeO4] ⋅ 1.5H2O in methanol leads to the formation of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n (1) which constitutes a new specimen of organotin(IV) selenate derivatives. In the solid state, complex 1 is arranged in polymeric zig-zag chains, composed of alternating Ph3Sn and SeO4 groups. In addition, pendant Ph3Sn ⋅ CH3OH moieties are branched along chains according to a syndiotactic organization and via Sn-O-Se connections. From a supramolecular point of view, intermolecular hydrogen bonds established between the selenate groups (uncoordinated oxygen) and the hydroxyl functions (CH3OH) of the pendant groups link the chains together.Diallo WalyCattey HélènePlasseraud LaurentDe Gruyterarticleorganotin(iv)seleniumsn-o-se moietycrystal structureinorganic chainChemistryQD1-999ENMain Group Metal Chemistry, Vol 44, Iss 1, Pp 213-217 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	organotin(iv) selenium sn-o-se moiety crystal structure inorganic chain Chemistry QD1-999
spellingShingle	organotin(iv) selenium sn-o-se moiety crystal structure inorganic chain Chemistry QD1-999 Diallo Waly Cattey Hélène Plasseraud Laurent Organotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n
description	Crystallization of [(Ph3Sn)2SeO4] ⋅ 1.5H2O in methanol leads to the formation of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n (1) which constitutes a new specimen of organotin(IV) selenate derivatives. In the solid state, complex 1 is arranged in polymeric zig-zag chains, composed of alternating Ph3Sn and SeO4 groups. In addition, pendant Ph3Sn ⋅ CH3OH moieties are branched along chains according to a syndiotactic organization and via Sn-O-Se connections. From a supramolecular point of view, intermolecular hydrogen bonds established between the selenate groups (uncoordinated oxygen) and the hydroxyl functions (CH3OH) of the pendant groups link the chains together.
format	article
author	Diallo Waly Cattey Hélène Plasseraud Laurent
author_facet	Diallo Waly Cattey Hélène Plasseraud Laurent
author_sort	Diallo Waly
title	Organotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n
title_short	Organotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n
title_full	Organotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n
title_fullStr	Organotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n
title_full_unstemmed	Organotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n
title_sort	organotin(iv) selenate derivatives – crystal structure of [{(ph3sn)2seo4} ⋅ ch3oh]n
publisher	De Gruyter
publishDate	2021
url	https://doaj.org/article/208c9d1615ef4cb29ed12b5b21cbee5d
work_keys_str_mv	AT diallowaly organotinivselenatederivativescrystalstructureofph3sn2seo4ch3ohn AT catteyhelene organotinivselenatederivativescrystalstructureofph3sn2seo4ch3ohn AT plasseraudlaurent organotinivselenatederivativescrystalstructureofph3sn2seo4ch3ohn
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Organotin(IV) selenate derivatives – Crystal structure of [{(Ph3Sn)2SeO4} ⋅ CH3OH]n

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