Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers

Development of strategies for the synthesis of pi-conjugated polymers is hampered by limited solubility. Here, the authors report a synthetic protocol based on the search for specific vibrational modes through an appropriate tailoring of the p-conjugation of the precursors, in order to increase the...

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Autores principales:	Bruno de la Torre, Adam Matěj, Ana Sánchez-Grande, Borja Cirera, Benjamin Mallada, Eider Rodríguez-Sánchez, José Santos, Jesús I. Mendieta-Moreno, Shayan Edalatmanesh, Koen Lauwaet, Michal Otyepka, Miroslav Medveď, Álvaro Buendía, Rodolfo Miranda, Nazario Martín, Pavel Jelínek, David Écija
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/20b3b59652a4494db7a1c5bcc5c1bf82
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spelling	oai:doaj.org-article:20b3b59652a4494db7a1c5bcc5c1bf822021-12-02T17:41:19ZTailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers10.1038/s41467-020-18371-22041-1723https://doaj.org/article/20b3b59652a4494db7a1c5bcc5c1bf822020-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-18371-2https://doaj.org/toc/2041-1723Development of strategies for the synthesis of pi-conjugated polymers is hampered by limited solubility. Here, the authors report a synthetic protocol based on the search for specific vibrational modes through an appropriate tailoring of the p-conjugation of the precursors, in order to increase the attempt frequency of a chemical reaction.Bruno de la TorreAdam MatějAna Sánchez-GrandeBorja CireraBenjamin MalladaEider Rodríguez-SánchezJosé SantosJesús I. Mendieta-MorenoShayan EdalatmaneshKoen LauwaetMichal OtyepkaMiroslav MedveďÁlvaro BuendíaRodolfo MirandaNazario MartínPavel JelínekDavid ÉcijaNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-8 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Bruno de la Torre Adam Matěj Ana Sánchez-Grande Borja Cirera Benjamin Mallada Eider Rodríguez-Sánchez José Santos Jesús I. Mendieta-Moreno Shayan Edalatmanesh Koen Lauwaet Michal Otyepka Miroslav Medveď Álvaro Buendía Rodolfo Miranda Nazario Martín Pavel Jelínek David Écija Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers
description	Development of strategies for the synthesis of pi-conjugated polymers is hampered by limited solubility. Here, the authors report a synthetic protocol based on the search for specific vibrational modes through an appropriate tailoring of the p-conjugation of the precursors, in order to increase the attempt frequency of a chemical reaction.
format	article
author	Bruno de la Torre Adam Matěj Ana Sánchez-Grande Borja Cirera Benjamin Mallada Eider Rodríguez-Sánchez José Santos Jesús I. Mendieta-Moreno Shayan Edalatmanesh Koen Lauwaet Michal Otyepka Miroslav Medveď Álvaro Buendía Rodolfo Miranda Nazario Martín Pavel Jelínek David Écija
author_facet	Bruno de la Torre Adam Matěj Ana Sánchez-Grande Borja Cirera Benjamin Mallada Eider Rodríguez-Sánchez José Santos Jesús I. Mendieta-Moreno Shayan Edalatmanesh Koen Lauwaet Michal Otyepka Miroslav Medveď Álvaro Buendía Rodolfo Miranda Nazario Martín Pavel Jelínek David Écija
author_sort	Bruno de la Torre
title	Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers
title_short	Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers
title_full	Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers
title_fullStr	Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers
title_full_unstemmed	Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers
title_sort	tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/20b3b59652a4494db7a1c5bcc5c1bf82
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Tailoring π-conjugation and vibrational modes to steer on-surface synthesis of pentalene-bridged ladder polymers

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