Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway
Perovskite manganites exhibit intriguing but poorly understood properties, including multiferroicity. Here, the authors synthesize a Ce3Mn8 cluster that structurally resembles a perovskite repeat unit, and use this molecular analogue to elucidate mechanisms driving bulk perovskite properties.
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Nature Portfolio
2017
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oai:doaj.org-article:210c04bedd2d42dea16094e43d6be31b2021-12-02T17:06:28ZMolecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway10.1038/s41467-017-00642-02041-1723https://doaj.org/article/210c04bedd2d42dea16094e43d6be31b2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00642-0https://doaj.org/toc/2041-1723Perovskite manganites exhibit intriguing but poorly understood properties, including multiferroicity. Here, the authors synthesize a Ce3Mn8 cluster that structurally resembles a perovskite repeat unit, and use this molecular analogue to elucidate mechanisms driving bulk perovskite properties.Annaliese E. ThuijsXiang-Guo LiYun-Peng WangKhalil A. AbboudX.-G. ZhangHai-Ping ChengGeorge ChristouNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-6 (2017) |
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Science Q Annaliese E. Thuijs Xiang-Guo Li Yun-Peng Wang Khalil A. Abboud X.-G. Zhang Hai-Ping Cheng George Christou Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway |
description |
Perovskite manganites exhibit intriguing but poorly understood properties, including multiferroicity. Here, the authors synthesize a Ce3Mn8 cluster that structurally resembles a perovskite repeat unit, and use this molecular analogue to elucidate mechanisms driving bulk perovskite properties. |
format |
article |
author |
Annaliese E. Thuijs Xiang-Guo Li Yun-Peng Wang Khalil A. Abboud X.-G. Zhang Hai-Ping Cheng George Christou |
author_facet |
Annaliese E. Thuijs Xiang-Guo Li Yun-Peng Wang Khalil A. Abboud X.-G. Zhang Hai-Ping Cheng George Christou |
author_sort |
Annaliese E. Thuijs |
title |
Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway |
title_short |
Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway |
title_full |
Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway |
title_fullStr |
Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway |
title_full_unstemmed |
Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway |
title_sort |
molecular analogue of the perovskite repeating unit and evidence for direct mniii-ceiv-mniii exchange coupling pathway |
publisher |
Nature Portfolio |
publishDate |
2017 |
url |
https://doaj.org/article/210c04bedd2d42dea16094e43d6be31b |
work_keys_str_mv |
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_version_ |
1718381602015281152 |