Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway

Perovskite manganites exhibit intriguing but poorly understood properties, including multiferroicity. Here, the authors synthesize a Ce3Mn8 cluster that structurally resembles a perovskite repeat unit, and use this molecular analogue to elucidate mechanisms driving bulk perovskite properties.

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Autores principales: Annaliese E. Thuijs, Xiang-Guo Li, Yun-Peng Wang, Khalil A. Abboud, X.-G. Zhang, Hai-Ping Cheng, George Christou
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Acceso en línea:https://doaj.org/article/210c04bedd2d42dea16094e43d6be31b
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spelling oai:doaj.org-article:210c04bedd2d42dea16094e43d6be31b2021-12-02T17:06:28ZMolecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway10.1038/s41467-017-00642-02041-1723https://doaj.org/article/210c04bedd2d42dea16094e43d6be31b2017-09-01T00:00:00Zhttps://doi.org/10.1038/s41467-017-00642-0https://doaj.org/toc/2041-1723Perovskite manganites exhibit intriguing but poorly understood properties, including multiferroicity. Here, the authors synthesize a Ce3Mn8 cluster that structurally resembles a perovskite repeat unit, and use this molecular analogue to elucidate mechanisms driving bulk perovskite properties.Annaliese E. ThuijsXiang-Guo LiYun-Peng WangKhalil A. AbboudX.-G. ZhangHai-Ping ChengGeorge ChristouNature PortfolioarticleScienceQENNature Communications, Vol 8, Iss 1, Pp 1-6 (2017)
institution DOAJ
collection DOAJ
language EN
topic Science
Q
spellingShingle Science
Q
Annaliese E. Thuijs
Xiang-Guo Li
Yun-Peng Wang
Khalil A. Abboud
X.-G. Zhang
Hai-Ping Cheng
George Christou
Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway
description Perovskite manganites exhibit intriguing but poorly understood properties, including multiferroicity. Here, the authors synthesize a Ce3Mn8 cluster that structurally resembles a perovskite repeat unit, and use this molecular analogue to elucidate mechanisms driving bulk perovskite properties.
format article
author Annaliese E. Thuijs
Xiang-Guo Li
Yun-Peng Wang
Khalil A. Abboud
X.-G. Zhang
Hai-Ping Cheng
George Christou
author_facet Annaliese E. Thuijs
Xiang-Guo Li
Yun-Peng Wang
Khalil A. Abboud
X.-G. Zhang
Hai-Ping Cheng
George Christou
author_sort Annaliese E. Thuijs
title Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway
title_short Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway
title_full Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway
title_fullStr Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway
title_full_unstemmed Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway
title_sort molecular analogue of the perovskite repeating unit and evidence for direct mniii-ceiv-mniii exchange coupling pathway
publisher Nature Portfolio
publishDate 2017
url https://doaj.org/article/210c04bedd2d42dea16094e43d6be31b
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