Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway

Molecular analogue of the perovskite repeating unit and evidence for direct MnIII-CeIV-MnIII exchange coupling pathway

Perovskite manganites exhibit intriguing but poorly understood properties, including multiferroicity. Here, the authors synthesize a Ce3Mn8 cluster that structurally resembles a perovskite repeat unit, and use this molecular analogue to elucidate mechanisms driving bulk perovskite properties.

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Autores principales: Annaliese E. Thuijs, Xiang-Guo Li, Yun-Peng Wang, Khalil A. Abboud, X.-G. Zhang, Hai-Ping Cheng, George Christou
Formato: article
Lenguaje:EN
Publicado: Nature Portfolio 2017
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Science
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Acceso en línea:https://doaj.org/article/210c04bedd2d42dea16094e43d6be31b
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