SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS

Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowin...

Descripción completa

Guardado en:

Detalles Bibliográficos
Autores principales:	MODOU SARR, AMINATA DIASSE-SARR, LIBASSE DIOP
Formato:	article
Lenguaje:	EN
Publicado:	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau 2020
Materias:	bidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architectures Technology T Engineering (General). Civil engineering (General) TA1-2040
Acceso en línea:	https://doaj.org/article/216a7b42f486423ead523fd250f24a64
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:216a7b42f486423ead523fd250f24a64
record_format	dspace
spelling	oai:doaj.org-article:216a7b42f486423ead523fd250f24a642021-12-02T19:52:42ZSYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS10.29081/jesr.v26i3.2272068-75592344-4932https://doaj.org/article/216a7b42f486423ead523fd250f24a642020-07-01T00:00:00Zhttp://www.jesr.ub.ro/1/article/view/227https://doaj.org/toc/2068-7559https://doaj.org/toc/2344-4932 Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowing (C6H5CH2)NH2)3O2C(CH2)2PO3 or [CyNH3(HO2POCH2-N(CH2 CO2H)2]2 and SnPh3Cl or SnCl2×2H2O to react in ethanolic media have been characterized by elemental analyses, infrared and Mossbauer techniques. The suggested structures, while considering the anionic counterpart, are discrete, dimeric, double and triple metallic components or of infinite chain types, the anion behaving as a monochelating, a bichelating or a bidentate ligand. In OH containing structures, when extra hydrogen bonds are considered, supramolecular architectures may be obtained. MODOU SARRAMINATA DIASSE-SARRLIBASSE DIOPAlma Mater Publishing House "Vasile Alecsandri" University of Bacauarticlebidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architecturesTechnologyTEngineering (General). Civil engineering (General)TA1-2040ENJournal of Engineering Studies and Research, Vol 26, Iss 3 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	bidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architectures Technology T Engineering (General). Civil engineering (General) TA1-2040
spellingShingle	bidentate, bichelating, hydrogen bonds, monochelating, PhPO3H-, Ph2PO2-, [O2C (CH2)2 PO3]3-[(HO2POCH2-N(CH2CO2H)2]-, infrared and Mossbauer techniques, supramolecular architectures Technology T Engineering (General). Civil engineering (General) TA1-2040 MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
description	Three organotin (IV) derivatives PhPO3HSnBu2Cl, SnBu2Ph2PO2Cl×3/2H2O, Sn(PhPO3)Cl2×2H2O obtained on allowing PhPO3H2 or propylammonium PhPO3H to react with SnBu2Cl2, SnCl2×2H2O and two adducts [(C6H5CH2)2NH2]3O2C(CH2)2PO3×3SnPh3Cl, [CyNH3(HO2POCH2-N(CH2CO2H)2]2×3SnCl4.2H2O×NH4Cl obtained on allowing (C6H5CH2)NH2)3O2C(CH2)2PO3 or [CyNH3(HO2POCH2-N(CH2 CO2H)2]2 and SnPh3Cl or SnCl2×2H2O to react in ethanolic media have been characterized by elemental analyses, infrared and Mossbauer techniques. The suggested structures, while considering the anionic counterpart, are discrete, dimeric, double and triple metallic components or of infinite chain types, the anion behaving as a monochelating, a bichelating or a bidentate ligand. In OH containing structures, when extra hydrogen bonds are considered, supramolecular architectures may be obtained.
format	article
author	MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP
author_facet	MODOU SARR AMINATA DIASSE-SARR LIBASSE DIOP
author_sort	MODOU SARR
title	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_short	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_full	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_fullStr	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_full_unstemmed	SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS
title_sort	synthesis and infrared study of some phenylphosphonate, diphenylphosphinate and acetatophosphonate new organotin (iv) derivatives and adducts
publisher	Alma Mater Publishing House "Vasile Alecsandri" University of Bacau
publishDate	2020
url	https://doaj.org/article/216a7b42f486423ead523fd250f24a64
work_keys_str_mv	AT modousarr synthesisandinfraredstudyofsomephenylphosphonatediphenylphosphinateandacetatophosphonateneworganotinivderivativesandadducts AT aminatadiassesarr synthesisandinfraredstudyofsomephenylphosphonatediphenylphosphinateandacetatophosphonateneworganotinivderivativesandadducts AT libassediop synthesisandinfraredstudyofsomephenylphosphonatediphenylphosphinateandacetatophosphonateneworganotinivderivativesandadducts
_version_	1718375887936684032

SYNTHESIS AND INFRARED STUDY OF SOME PHENYLPHOSPHONATE, DIPHENYLPHOSPHINATE AND ACETATOPHOSPHONATE NEW ORGANOTIN (IV) DERIVATIVES AND ADDUCTS

Ejemplares similares