Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes

In comparison to their neutral or anionic counterparts, examples of cationic boron clusters remain scarce. Here, the authors prepare a variety of cationic polyhedral boranes by reacting closo-10-vertex carboranes with N-heterocyclic carbenes; the resulting open-cage cationic nido- arachno- or closo-...

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Main Authors:	Jan Vrána, Josef Holub, Maksim A. Samsonov, Zdeňka Růžičková, Josef Cvačka, Michael L. McKee, Jindřich Fanfrlík, Drahomír Hnyk, Aleš Růžička
Format:	article
Language:	EN
Published:	Nature Portfolio 2021
Subjects:	Science Q
Online Access:	https://doaj.org/article/21c4119fa0b647f68aac02e4a0513d98
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spelling	oai:doaj.org-article:21c4119fa0b647f68aac02e4a0513d982021-12-02T18:01:16ZAccess to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes10.1038/s41467-021-25277-02041-1723https://doaj.org/article/21c4119fa0b647f68aac02e4a0513d982021-08-01T00:00:00Zhttps://doi.org/10.1038/s41467-021-25277-0https://doaj.org/toc/2041-1723In comparison to their neutral or anionic counterparts, examples of cationic boron clusters remain scarce. Here, the authors prepare a variety of cationic polyhedral boranes by reacting closo-10-vertex carboranes with N-heterocyclic carbenes; the resulting open-cage cationic nido- arachno- or closo- derivatives are water soluble, which may enable unprecedented applications.Jan VránaJosef HolubMaksim A. SamsonovZdeňka RůžičkováJosef CvačkaMichael L. McKeeJindřich FanfrlíkDrahomír HnykAleš RůžičkaNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-7 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Jan Vrána Josef Holub Maksim A. Samsonov Zdeňka Růžičková Josef Cvačka Michael L. McKee Jindřich Fanfrlík Drahomír Hnyk Aleš Růžička Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes
description	In comparison to their neutral or anionic counterparts, examples of cationic boron clusters remain scarce. Here, the authors prepare a variety of cationic polyhedral boranes by reacting closo-10-vertex carboranes with N-heterocyclic carbenes; the resulting open-cage cationic nido- arachno- or closo- derivatives are water soluble, which may enable unprecedented applications.
format	article
author	Jan Vrána Josef Holub Maksim A. Samsonov Zdeňka Růžičková Josef Cvačka Michael L. McKee Jindřich Fanfrlík Drahomír Hnyk Aleš Růžička
author_facet	Jan Vrána Josef Holub Maksim A. Samsonov Zdeňka Růžičková Josef Cvačka Michael L. McKee Jindřich Fanfrlík Drahomír Hnyk Aleš Růžička
author_sort	Jan Vrána
title	Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes
title_short	Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes
title_full	Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes
title_fullStr	Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes
title_full_unstemmed	Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes
title_sort	access to cationic polyhedral carboranes via dynamic cage surgery with n-heterocyclic carbenes
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/21c4119fa0b647f68aac02e4a0513d98
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Access to cationic polyhedral carboranes via dynamic cage surgery with N-heterocyclic carbenes

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