Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater

The effect of pH on the corrosion and repassivation behavior of TA2 in simulated seawater was studied using electrochemical tests, immersion experiments, and surface morphology topology analysis. The results show that E<sub>corr</sub> and R<sub>f</sub> increased while i<su...

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Autores principales: Yingxiao Zhang, Tingting Yan, Lin Fan, Zhiyong Liu, Longfei Song, Xiaogang Li
Formato: article
Lenguaje:EN
Publicado: MDPI AG 2021
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Acceso en línea:https://doaj.org/article/22359719d5304861982608dac617eeed
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spelling oai:doaj.org-article:22359719d5304861982608dac617eeed2021-11-25T18:13:22ZEffect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater10.3390/ma142267641996-1944https://doaj.org/article/22359719d5304861982608dac617eeed2021-11-01T00:00:00Zhttps://www.mdpi.com/1996-1944/14/22/6764https://doaj.org/toc/1996-1944The effect of pH on the corrosion and repassivation behavior of TA2 in simulated seawater was studied using electrochemical tests, immersion experiments, and surface morphology topology analysis. The results show that E<sub>corr</sub> and R<sub>f</sub> increased while i<sub>pass</sub> and weight loss rate decreased as the pH of simulated seawater increased. The TA2 passive film was determined to be mainly composed of a large amount of TiO<sub>2</sub> and a small amount of TiO. The repassivation function of TA2 can be expressed as <i>E</i> = −0.1375 + 0.0532ln(<i>t</i> − 1.241) for a simulated seawater pH of 8.2. The parameter b, which represents the slope of the potential–time curve during the friction electrode test, was used to evaluate the repassivation behavior of TA2. The increase in pH value was observed to promote the repassivation speed of the passive film, which is beneficial to the corrosion resistance of TA2.Yingxiao ZhangTingting YanLin FanZhiyong LiuLongfei SongXiaogang LiMDPI AGarticleTA2corrosion behaviorrepassivation behaviorsimulated seawater environmentTechnologyTElectrical engineering. Electronics. Nuclear engineeringTK1-9971Engineering (General). Civil engineering (General)TA1-2040MicroscopyQH201-278.5Descriptive and experimental mechanicsQC120-168.85ENMaterials, Vol 14, Iss 6764, p 6764 (2021)
institution DOAJ
collection DOAJ
language EN
topic TA2
corrosion behavior
repassivation behavior
simulated seawater environment
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
spellingShingle TA2
corrosion behavior
repassivation behavior
simulated seawater environment
Technology
T
Electrical engineering. Electronics. Nuclear engineering
TK1-9971
Engineering (General). Civil engineering (General)
TA1-2040
Microscopy
QH201-278.5
Descriptive and experimental mechanics
QC120-168.85
Yingxiao Zhang
Tingting Yan
Lin Fan
Zhiyong Liu
Longfei Song
Xiaogang Li
Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
description The effect of pH on the corrosion and repassivation behavior of TA2 in simulated seawater was studied using electrochemical tests, immersion experiments, and surface morphology topology analysis. The results show that E<sub>corr</sub> and R<sub>f</sub> increased while i<sub>pass</sub> and weight loss rate decreased as the pH of simulated seawater increased. The TA2 passive film was determined to be mainly composed of a large amount of TiO<sub>2</sub> and a small amount of TiO. The repassivation function of TA2 can be expressed as <i>E</i> = −0.1375 + 0.0532ln(<i>t</i> − 1.241) for a simulated seawater pH of 8.2. The parameter b, which represents the slope of the potential–time curve during the friction electrode test, was used to evaluate the repassivation behavior of TA2. The increase in pH value was observed to promote the repassivation speed of the passive film, which is beneficial to the corrosion resistance of TA2.
format article
author Yingxiao Zhang
Tingting Yan
Lin Fan
Zhiyong Liu
Longfei Song
Xiaogang Li
author_facet Yingxiao Zhang
Tingting Yan
Lin Fan
Zhiyong Liu
Longfei Song
Xiaogang Li
author_sort Yingxiao Zhang
title Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_short Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_full Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_fullStr Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_full_unstemmed Effect of pH on the Corrosion and Repassivation Behavior of TA2 in Simulated Seawater
title_sort effect of ph on the corrosion and repassivation behavior of ta2 in simulated seawater
publisher MDPI AG
publishDate 2021
url https://doaj.org/article/22359719d5304861982608dac617eeed
work_keys_str_mv AT yingxiaozhang effectofphonthecorrosionandrepassivationbehaviorofta2insimulatedseawater
AT tingtingyan effectofphonthecorrosionandrepassivationbehaviorofta2insimulatedseawater
AT linfan effectofphonthecorrosionandrepassivationbehaviorofta2insimulatedseawater
AT zhiyongliu effectofphonthecorrosionandrepassivationbehaviorofta2insimulatedseawater
AT longfeisong effectofphonthecorrosionandrepassivationbehaviorofta2insimulatedseawater
AT xiaogangli effectofphonthecorrosionandrepassivationbehaviorofta2insimulatedseawater
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