Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis

Azoxy bonds are frequently found in liquid crystals, chemical intermediates, dyes, agrochemicals and pharmaceuticals. Here, the authors investigated azoxy bond formation by the non-heme diiron N-oxygenase AzoC in azoxymycin biosynthesis and show that the nitroso group plays a key part in it.

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Autores principales:	Yuan-Yang Guo, Zhen-Hua Li, Tian-Yu Xia, Yi-Ling Du, Xu-Ming Mao, Yong-Quan Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2019
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/226e496179d24ce0b09894bc7d0f768e
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spelling	oai:doaj.org-article:226e496179d24ce0b09894bc7d0f768e2021-12-02T14:39:00ZMolecular mechanism of azoxy bond formation for azoxymycins biosynthesis10.1038/s41467-019-12250-12041-1723https://doaj.org/article/226e496179d24ce0b09894bc7d0f768e2019-10-01T00:00:00Zhttps://doi.org/10.1038/s41467-019-12250-1https://doaj.org/toc/2041-1723Azoxy bonds are frequently found in liquid crystals, chemical intermediates, dyes, agrochemicals and pharmaceuticals. Here, the authors investigated azoxy bond formation by the non-heme diiron N-oxygenase AzoC in azoxymycin biosynthesis and show that the nitroso group plays a key part in it.Yuan-Yang GuoZhen-Hua LiTian-Yu XiaYi-Ling DuXu-Ming MaoYong-Quan LiNature PortfolioarticleScienceQENNature Communications, Vol 10, Iss 1, Pp 1-9 (2019)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Yuan-Yang Guo Zhen-Hua Li Tian-Yu Xia Yi-Ling Du Xu-Ming Mao Yong-Quan Li Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis
description	Azoxy bonds are frequently found in liquid crystals, chemical intermediates, dyes, agrochemicals and pharmaceuticals. Here, the authors investigated azoxy bond formation by the non-heme diiron N-oxygenase AzoC in azoxymycin biosynthesis and show that the nitroso group plays a key part in it.
format	article
author	Yuan-Yang Guo Zhen-Hua Li Tian-Yu Xia Yi-Ling Du Xu-Ming Mao Yong-Quan Li
author_facet	Yuan-Yang Guo Zhen-Hua Li Tian-Yu Xia Yi-Ling Du Xu-Ming Mao Yong-Quan Li
author_sort	Yuan-Yang Guo
title	Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis
title_short	Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis
title_full	Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis
title_fullStr	Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis
title_full_unstemmed	Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis
title_sort	molecular mechanism of azoxy bond formation for azoxymycins biosynthesis
publisher	Nature Portfolio
publishDate	2019
url	https://doaj.org/article/226e496179d24ce0b09894bc7d0f768e
work_keys_str_mv	AT yuanyangguo molecularmechanismofazoxybondformationforazoxymycinsbiosynthesis AT zhenhuali molecularmechanismofazoxybondformationforazoxymycinsbiosynthesis AT tianyuxia molecularmechanismofazoxybondformationforazoxymycinsbiosynthesis AT yilingdu molecularmechanismofazoxybondformationforazoxymycinsbiosynthesis AT xumingmao molecularmechanismofazoxybondformationforazoxymycinsbiosynthesis AT yongquanli molecularmechanismofazoxybondformationforazoxymycinsbiosynthesis
_version_	1718390760251850752

Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis

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