Molecular mechanism of azoxy bond formation for azoxymycins biosynthesis
Azoxy bonds are frequently found in liquid crystals, chemical intermediates, dyes, agrochemicals and pharmaceuticals. Here, the authors investigated azoxy bond formation by the non-heme diiron N-oxygenase AzoC in azoxymycin biosynthesis and show that the nitroso group plays a key part in it.
Guardado en:
Autores principales: | Yuan-Yang Guo, Zhen-Hua Li, Tian-Yu Xia, Yi-Ling Du, Xu-Ming Mao, Yong-Quan Li |
---|---|
Formato: | article |
Lenguaje: | EN |
Publicado: |
Nature Portfolio
2019
|
Materias: | |
Acceso en línea: | https://doaj.org/article/226e496179d24ce0b09894bc7d0f768e |
Etiquetas: |
Agregar Etiqueta
Sin Etiquetas, Sea el primero en etiquetar este registro!
|
Ejemplares similares
-
Light-tuned selective photosynthesis of azo- and azoxy-aromatics using graphitic C3N4
por: Yitao Dai, et al.
Publicado: (2018) -
Oxepinamide F biosynthesis involves enzymatic d-aminoacyl epimerization, 3H-oxepin formation, and hydroxylation induced double bond migration
por: Liujuan Zheng, et al.
Publicado: (2020) -
Molecular basis of dimer formation during the biosynthesis of benzofluorene-containing atypical angucyclines
por: Chunshuai Huang, et al.
Publicado: (2018) -
On-surface synthesis of poly(p-phenylene ethynylene) molecular wires via in situ formation of carbon-carbon triple bond
por: Chen-Hui Shu, et al.
Publicado: (2018) -
A radical S-adenosyl-L-methionine enzyme and a methyltransferase catalyze cyclopropane formation in natural product biosynthesis
por: Wen-Bing Jin, et al.
Publicado: (2018)