Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature

The high bond energies of C–O bonds in biomass and its derivatives make their cleavage very challenging. Here, the authors report a photoredox-catalyzed C–O bond cleavage in diaryl ethers by acidolysis with an aryl carboxylic acid followed by hydrolysis in a one-pot manner.

Guardado en:

Detalles Bibliográficos
Autores principales:	Fang-Fang Tan, Xiao-Ya He, Wan-Fa Tian, Yang Li
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2020
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/227ac2943c534b5c86c6003287a40c63
Etiquetas:	Agregar Etiqueta Sin Etiquetas, Sea el primero en etiquetar este registro!

id	oai:doaj.org-article:227ac2943c534b5c86c6003287a40c63
record_format	dspace
spelling	oai:doaj.org-article:227ac2943c534b5c86c6003287a40c632021-12-02T17:32:11ZVisible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature10.1038/s41467-020-19944-x2041-1723https://doaj.org/article/227ac2943c534b5c86c6003287a40c632020-11-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-19944-xhttps://doaj.org/toc/2041-1723The high bond energies of C–O bonds in biomass and its derivatives make their cleavage very challenging. Here, the authors report a photoredox-catalyzed C–O bond cleavage in diaryl ethers by acidolysis with an aryl carboxylic acid followed by hydrolysis in a one-pot manner.Fang-Fang TanXiao-Ya HeWan-Fa TianYang LiNature PortfolioarticleScienceQENNature Communications, Vol 11, Iss 1, Pp 1-11 (2020)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Fang-Fang Tan Xiao-Ya He Wan-Fa Tian Yang Li Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature
description	The high bond energies of C–O bonds in biomass and its derivatives make their cleavage very challenging. Here, the authors report a photoredox-catalyzed C–O bond cleavage in diaryl ethers by acidolysis with an aryl carboxylic acid followed by hydrolysis in a one-pot manner.
format	article
author	Fang-Fang Tan Xiao-Ya He Wan-Fa Tian Yang Li
author_facet	Fang-Fang Tan Xiao-Ya He Wan-Fa Tian Yang Li
author_sort	Fang-Fang Tan
title	Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature
title_short	Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature
title_full	Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature
title_fullStr	Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature
title_full_unstemmed	Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature
title_sort	visible-light photoredox-catalyzed c–o bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature
publisher	Nature Portfolio
publishDate	2020
url	https://doaj.org/article/227ac2943c534b5c86c6003287a40c63
work_keys_str_mv	AT fangfangtan visiblelightphotoredoxcatalyzedcobondcleavageofdiarylethersbyacridiniumphotocatalystsatroomtemperature AT xiaoyahe visiblelightphotoredoxcatalyzedcobondcleavageofdiarylethersbyacridiniumphotocatalystsatroomtemperature AT wanfatian visiblelightphotoredoxcatalyzedcobondcleavageofdiarylethersbyacridiniumphotocatalystsatroomtemperature AT yangli visiblelightphotoredoxcatalyzedcobondcleavageofdiarylethersbyacridiniumphotocatalystsatroomtemperature
_version_	1718380354829549568

Visible-light photoredox-catalyzed C–O bond cleavage of diaryl ethers by acridinium photocatalysts at room temperature

Ejemplares similares