Cobalt Electroplating in Choline Chloride-ethylene Glycol: A Comparative Study
In this work, cobalt electroplating from homogeneous oxidation of cobalt powder via iodine as a chemical oxidizing agent and from CoCl2·6H2O in choline chloride-ethylene glycol electrolytic bath was carried out at 90 °C. As relatively high temperature and corrosion resistive coating material, cobalt...
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The Electrochemical Society of Japan
2021
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oai:doaj.org-article:2292ad6a197242e28b94ff4d8de680fd2021-11-05T00:17:27ZCobalt Electroplating in Choline Chloride-ethylene Glycol: A Comparative Study2186-245110.5796/electrochemistry.21-00087https://doaj.org/article/2292ad6a197242e28b94ff4d8de680fd2021-11-01T00:00:00Zhttps://www.jstage.jst.go.jp/article/electrochemistry/89/6/89_21-00087/_html/-char/enhttps://doaj.org/toc/2186-2451In this work, cobalt electroplating from homogeneous oxidation of cobalt powder via iodine as a chemical oxidizing agent and from CoCl2·6H2O in choline chloride-ethylene glycol electrolytic bath was carried out at 90 °C. As relatively high temperature and corrosion resistive coating material, cobalt electroplating was performed. A number of electrochemical, spectroscopic and microscopic techniques, such as, cyclic voltammetry (CV), chronocoulometry, UV-visible spectroscopy and scanning electron microscopy (SEM) were used in fabrication and characterizations of the electroplated cobalt. The progressive nucleation mechanism is followed in case of cobalt electroplating using cobalt powder in the presence of iodine. The mirror-like surface (i.e., smooth surface) surface has been obtained when cobalt powder utilized with the aid of iodine as shown in the SEM images. The effectiveness of the existence of iodine and cobalt powder was evidenced from chronocoulometry in which huge number of charge was released during the electrochemical course.Jamil A. JUMAWrya O. KARIMShujahadeen A. AZIZKhalid M. OMERThe Electrochemical Society of Japanarticleelectroplatingcobalt powderiodinedeep eutectic solventTechnologyTPhysical and theoretical chemistryQD450-801ENJAElectrochemistry, Vol 89, Iss 6, Pp 602-605 (2021) |
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electroplating cobalt powder iodine deep eutectic solvent Technology T Physical and theoretical chemistry QD450-801 |
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electroplating cobalt powder iodine deep eutectic solvent Technology T Physical and theoretical chemistry QD450-801 Jamil A. JUMA Wrya O. KARIM Shujahadeen A. AZIZ Khalid M. OMER Cobalt Electroplating in Choline Chloride-ethylene Glycol: A Comparative Study |
description |
In this work, cobalt electroplating from homogeneous oxidation of cobalt powder via iodine as a chemical oxidizing agent and from CoCl2·6H2O in choline chloride-ethylene glycol electrolytic bath was carried out at 90 °C. As relatively high temperature and corrosion resistive coating material, cobalt electroplating was performed. A number of electrochemical, spectroscopic and microscopic techniques, such as, cyclic voltammetry (CV), chronocoulometry, UV-visible spectroscopy and scanning electron microscopy (SEM) were used in fabrication and characterizations of the electroplated cobalt. The progressive nucleation mechanism is followed in case of cobalt electroplating using cobalt powder in the presence of iodine. The mirror-like surface (i.e., smooth surface) surface has been obtained when cobalt powder utilized with the aid of iodine as shown in the SEM images. The effectiveness of the existence of iodine and cobalt powder was evidenced from chronocoulometry in which huge number of charge was released during the electrochemical course. |
format |
article |
author |
Jamil A. JUMA Wrya O. KARIM Shujahadeen A. AZIZ Khalid M. OMER |
author_facet |
Jamil A. JUMA Wrya O. KARIM Shujahadeen A. AZIZ Khalid M. OMER |
author_sort |
Jamil A. JUMA |
title |
Cobalt Electroplating in Choline Chloride-ethylene Glycol: A Comparative Study |
title_short |
Cobalt Electroplating in Choline Chloride-ethylene Glycol: A Comparative Study |
title_full |
Cobalt Electroplating in Choline Chloride-ethylene Glycol: A Comparative Study |
title_fullStr |
Cobalt Electroplating in Choline Chloride-ethylene Glycol: A Comparative Study |
title_full_unstemmed |
Cobalt Electroplating in Choline Chloride-ethylene Glycol: A Comparative Study |
title_sort |
cobalt electroplating in choline chloride-ethylene glycol: a comparative study |
publisher |
The Electrochemical Society of Japan |
publishDate |
2021 |
url |
https://doaj.org/article/2292ad6a197242e28b94ff4d8de680fd |
work_keys_str_mv |
AT jamilajuma cobaltelectroplatingincholinechlorideethyleneglycolacomparativestudy AT wryaokarim cobaltelectroplatingincholinechlorideethyleneglycolacomparativestudy AT shujahadeenaaziz cobaltelectroplatingincholinechlorideethyleneglycolacomparativestudy AT khalidmomer cobaltelectroplatingincholinechlorideethyleneglycolacomparativestudy |
_version_ |
1718444517270487040 |