Straightforward and rapid Petasis multicomponent reactions in deep eutectic solvent

Deep eutectic solvents (DESs) have emerged as a promising, inexpensive, safe, renewable, and biodegradable alternative to harmful organic solvents as a premise for the green industrial transformation. An efficient and straightforward one-pot three-component Petasis reactions of salicylaldehyde deriv...

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Autores principales:	Najmedin Azizi, Elham Farhadi
Formato:	article
Lenguaje:	EN
Publicado:	Elsevier 2021
Materias:	Deep eutectic solvent Petasis Arylboronic acids Multicomponent reaction Mannich reaction Chemistry QD1-999
Acceso en línea:	https://doaj.org/article/22acc32414634d01bd1105db389954d7
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spelling	oai:doaj.org-article:22acc32414634d01bd1105db389954d72021-11-20T05:13:44ZStraightforward and rapid Petasis multicomponent reactions in deep eutectic solvent2666-086510.1016/j.crgsc.2021.100220https://doaj.org/article/22acc32414634d01bd1105db389954d72021-01-01T00:00:00Zhttp://www.sciencedirect.com/science/article/pii/S2666086521001673https://doaj.org/toc/2666-0865Deep eutectic solvents (DESs) have emerged as a promising, inexpensive, safe, renewable, and biodegradable alternative to harmful organic solvents as a premise for the green industrial transformation. An efficient and straightforward one-pot three-component Petasis reactions of salicylaldehyde derivatives with various amines and boronic acids in the glycerol/choline chloride-based deep eutectic solvent (DES) were developed. Wide varieties of Mannich-type products were obtained in acceptable to excellent yields under mild conditions and short reaction times. The exceptional features of this procedure involve facile and environmentally friendly solvent, recyclable reaction media, and wide tolerance toward functional groups. The DES system can be recycled four times without significantly decreasing the yields.Najmedin AziziElham FarhadiElsevierarticleDeep eutectic solventPetasisArylboronic acidsMulticomponent reactionMannich reactionChemistryQD1-999ENCurrent Research in Green and Sustainable Chemistry, Vol 4, Iss , Pp 100220- (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Deep eutectic solvent Petasis Arylboronic acids Multicomponent reaction Mannich reaction Chemistry QD1-999
spellingShingle	Deep eutectic solvent Petasis Arylboronic acids Multicomponent reaction Mannich reaction Chemistry QD1-999 Najmedin Azizi Elham Farhadi Straightforward and rapid Petasis multicomponent reactions in deep eutectic solvent
description	Deep eutectic solvents (DESs) have emerged as a promising, inexpensive, safe, renewable, and biodegradable alternative to harmful organic solvents as a premise for the green industrial transformation. An efficient and straightforward one-pot three-component Petasis reactions of salicylaldehyde derivatives with various amines and boronic acids in the glycerol/choline chloride-based deep eutectic solvent (DES) were developed. Wide varieties of Mannich-type products were obtained in acceptable to excellent yields under mild conditions and short reaction times. The exceptional features of this procedure involve facile and environmentally friendly solvent, recyclable reaction media, and wide tolerance toward functional groups. The DES system can be recycled four times without significantly decreasing the yields.
format	article
author	Najmedin Azizi Elham Farhadi
author_facet	Najmedin Azizi Elham Farhadi
author_sort	Najmedin Azizi
title	Straightforward and rapid Petasis multicomponent reactions in deep eutectic solvent
title_short	Straightforward and rapid Petasis multicomponent reactions in deep eutectic solvent
title_full	Straightforward and rapid Petasis multicomponent reactions in deep eutectic solvent
title_fullStr	Straightforward and rapid Petasis multicomponent reactions in deep eutectic solvent
title_full_unstemmed	Straightforward and rapid Petasis multicomponent reactions in deep eutectic solvent
title_sort	straightforward and rapid petasis multicomponent reactions in deep eutectic solvent
publisher	Elsevier
publishDate	2021
url	https://doaj.org/article/22acc32414634d01bd1105db389954d7
work_keys_str_mv	AT najmedinazizi straightforwardandrapidpetasismulticomponentreactionsindeepeutecticsolvent AT elhamfarhadi straightforwardandrapidpetasismulticomponentreactionsindeepeutecticsolvent
_version_	1718419470391705600

Straightforward and rapid Petasis multicomponent reactions in deep eutectic solvent

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