Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene

Baird’s rules say that the first triplet state of benzene displays antiaromatic character. Here, the authors exploit this to show that aromatic molecules can undergo rapid transfer hydrogenation or silylations without the need for metal catalysts when photochemcially excited into this state.

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Autores principales:	Raffaello Papadakis, Hu Li, Joakim Bergman, Anna Lundstedt, Kjell Jorner, Rabia Ayub, Soumyajyoti Haldar, Burkhard O. Jahn, Aleksandra Denisova, Burkhard Zietz, Roland Lindh, Biplab Sanyal, Helena Grennberg, Klaus Leifer, Henrik Ottosson
Formato:	article
Lenguaje:	EN
Publicado:	Nature Portfolio 2016
Materias:	Science Q
Acceso en línea:	https://doaj.org/article/22c966a83af84406bcc41b47bcd48edd
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spelling	oai:doaj.org-article:22c966a83af84406bcc41b47bcd48edd2021-12-02T14:39:32ZMetal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene10.1038/ncomms129622041-1723https://doaj.org/article/22c966a83af84406bcc41b47bcd48edd2016-10-01T00:00:00Zhttps://doi.org/10.1038/ncomms12962https://doaj.org/toc/2041-1723Baird’s rules say that the first triplet state of benzene displays antiaromatic character. Here, the authors exploit this to show that aromatic molecules can undergo rapid transfer hydrogenation or silylations without the need for metal catalysts when photochemcially excited into this state.Raffaello PapadakisHu LiJoakim BergmanAnna LundstedtKjell JornerRabia AyubSoumyajyoti HaldarBurkhard O. JahnAleksandra DenisovaBurkhard ZietzRoland LindhBiplab SanyalHelena GrennbergKlaus LeiferHenrik OttossonNature PortfolioarticleScienceQENNature Communications, Vol 7, Iss 1, Pp 1-10 (2016)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Raffaello Papadakis Hu Li Joakim Bergman Anna Lundstedt Kjell Jorner Rabia Ayub Soumyajyoti Haldar Burkhard O. Jahn Aleksandra Denisova Burkhard Zietz Roland Lindh Biplab Sanyal Helena Grennberg Klaus Leifer Henrik Ottosson Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene
description	Baird’s rules say that the first triplet state of benzene displays antiaromatic character. Here, the authors exploit this to show that aromatic molecules can undergo rapid transfer hydrogenation or silylations without the need for metal catalysts when photochemcially excited into this state.
format	article
author	Raffaello Papadakis Hu Li Joakim Bergman Anna Lundstedt Kjell Jorner Rabia Ayub Soumyajyoti Haldar Burkhard O. Jahn Aleksandra Denisova Burkhard Zietz Roland Lindh Biplab Sanyal Helena Grennberg Klaus Leifer Henrik Ottosson
author_facet	Raffaello Papadakis Hu Li Joakim Bergman Anna Lundstedt Kjell Jorner Rabia Ayub Soumyajyoti Haldar Burkhard O. Jahn Aleksandra Denisova Burkhard Zietz Roland Lindh Biplab Sanyal Helena Grennberg Klaus Leifer Henrik Ottosson
author_sort	Raffaello Papadakis
title	Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene
title_short	Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene
title_full	Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene
title_fullStr	Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene
title_full_unstemmed	Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene
title_sort	metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene
publisher	Nature Portfolio
publishDate	2016
url	https://doaj.org/article/22c966a83af84406bcc41b47bcd48edd
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Metal-free photochemical silylations and transfer hydrogenations of benzenoid hydrocarbons and graphene

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