Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes

Manganese-based hydrogenation catalysts are sensitive to high temperatures and may degrade under industrially relevant conditions. Here, the authors report a highly efficient manganese pincer pre-catalyst displaying high TOF values (up to 41 000 h−1) and stability (TON up to 200 000) at loadings as...

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Auteurs principaux:	Wenjun Yang, Ivan Yu. Chernyshov, Robin K. A. van Schendel, Manuela Weber, Christian Müller, Georgy A. Filonenko, Evgeny A. Pidko
Format:	article
Langue:	EN
Publié:	Nature Portfolio 2021
Sujets:	Science Q
Accès en ligne:	https://doaj.org/article/2333ee82b085469698a0e16aa50c9ae0
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id	oai:doaj.org-article:2333ee82b085469698a0e16aa50c9ae0
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spelling	oai:doaj.org-article:2333ee82b085469698a0e16aa50c9ae02021-12-02T11:46:02ZRobust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes10.1038/s41467-020-20168-22041-1723https://doaj.org/article/2333ee82b085469698a0e16aa50c9ae02021-01-01T00:00:00Zhttps://doi.org/10.1038/s41467-020-20168-2https://doaj.org/toc/2041-1723Manganese-based hydrogenation catalysts are sensitive to high temperatures and may degrade under industrially relevant conditions. Here, the authors report a highly efficient manganese pincer pre-catalyst displaying high TOF values (up to 41 000 h−1) and stability (TON up to 200 000) at loadings as low as 5-200 ppm.Wenjun YangIvan Yu. ChernyshovRobin K. A. van SchendelManuela WeberChristian MüllerGeorgy A. FilonenkoEvgeny A. PidkoNature PortfolioarticleScienceQENNature Communications, Vol 12, Iss 1, Pp 1-8 (2021)
institution	DOAJ
collection	DOAJ
language	EN
topic	Science Q
spellingShingle	Science Q Wenjun Yang Ivan Yu. Chernyshov Robin K. A. van Schendel Manuela Weber Christian Müller Georgy A. Filonenko Evgeny A. Pidko Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
description	Manganese-based hydrogenation catalysts are sensitive to high temperatures and may degrade under industrially relevant conditions. Here, the authors report a highly efficient manganese pincer pre-catalyst displaying high TOF values (up to 41 000 h−1) and stability (TON up to 200 000) at loadings as low as 5-200 ppm.
format	article
author	Wenjun Yang Ivan Yu. Chernyshov Robin K. A. van Schendel Manuela Weber Christian Müller Georgy A. Filonenko Evgeny A. Pidko
author_facet	Wenjun Yang Ivan Yu. Chernyshov Robin K. A. van Schendel Manuela Weber Christian Müller Georgy A. Filonenko Evgeny A. Pidko
author_sort	Wenjun Yang
title	Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_short	Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_full	Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_fullStr	Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_full_unstemmed	Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes
title_sort	robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor mn(i) pincer complexes
publisher	Nature Portfolio
publishDate	2021
url	https://doaj.org/article/2333ee82b085469698a0e16aa50c9ae0
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_version_	1718395214859599872

Robust and efficient hydrogenation of carbonyl compounds catalysed by mixed donor Mn(I) pincer complexes

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