Ability of Lewis Acids with Shallow σ-Holes to Engage in Chalcogen Bonds in Different Environments
Molecules of the type XYT = Ch (T = C, Si, Ge; Ch = S, Se; X,Y = H, CH<sub>3</sub>, Cl, Br, I) contain a σ-hole along the T = Ch bond extension. This hole can engage with the N lone pair of NCH and NCCH<sub>3</sub> so as to form a chalcogen bond. In the case of T = C, these b...
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Main Authors: | Rafał Wysokiński, Wiktor Zierkiewicz, Mariusz Michalczyk, Steve Scheiner |
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Format: | article |
Language: | EN |
Published: |
MDPI AG
2021
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Online Access: | https://doaj.org/article/2383cf7e9f3444df9bb5f3060cb1cf34 |
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