Ability of Lewis Acids with Shallow σ-Holes to Engage in Chalcogen Bonds in Different Environments

Molecules of the type XYT = Ch (T = C, Si, Ge; Ch = S, Se; X,Y = H, CH<sub>3</sub>, Cl, Br, I) contain a σ-hole along the T = Ch bond extension. This hole can engage with the N lone pair of NCH and NCCH<sub>3</sub> so as to form a chalcogen bond. In the case of T = C, these b...

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Bibliographic Details
Main Authors: Rafał Wysokiński, Wiktor Zierkiewicz, Mariusz Michalczyk, Steve Scheiner
Format: article
Language:EN
Published: MDPI AG 2021
Subjects:
AIM
Online Access:https://doaj.org/article/2383cf7e9f3444df9bb5f3060cb1cf34
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